NH3 release during the snow evaporation process in typical cities in Northeast China

• Published in: Scientific reports 2025-01, Vol.15 (1), p.201-17, Article 201
• Main Authors: Liu, Xiaoteng, Jia, Hongsheng, Zhao, Yunze, Zhang, Yachao, Hou, Haodong, Xu, Yingying
• Format: Article
• Language: English
• Subjects: 704/172; 704/172/169; 704/172/169/895; Air pollution; Air quality; Air quality measurements; Ammonia; Ammonium; Ammonium salts; Atmosphere; Atmospheric boundary layer; Boundary layers; Chemical composition of surface snow; Evaporation; Fluctuations; Functional areas; Humanities and Social Sciences; Industrial areas; Influencing factors of NH3 evaporation; multidisciplinary; NH3 conversion ratio; Particulate matter; Residential areas; Science; Science (multidisciplinary); Snow; Snow evaporation or sublimation; Snowmelt; Sodium chloride; Sublimation; Wet deposition; Wind speed
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-024-83991-3

NH 3  is the most important alkaline gas in the atmosphere and functions as a precursor to secondary ammonium salts. Therefore, identifying its sources and quantifying its emissions is imperative. NH 4 + represents a principal component of atmospheric particulate pollutants. As particulate matter acts as a condensation nucleus for wet deposition, the NH 4 + concentrations in precipitation are typically elevated. During the evaporation process of wet deposition, NH 4 + is likely to be re-emitted as a gas (NH 3 ). In Northeast China, heavy and frequent snowfall occurs, making it crucial to elucidate the NH 3 release flux and the factors influencing this release during the snow evaporation process in representative cities of this region. This study collected snow samples from five notable snowfall events in Changchun, Jilin Province that occurred from November 2023 to March 2024, to conduct indoor simulated evaporation experiments (among them, the actual phase changes of two snowfall events consisted mainly of evaporation, whereas those of the other three events consisted mainly of sublimation). The results indicated that during the snow evaporation process, the average ratio ( R ) of NH 4 +  re-emitted as NH 3 was 39.28 ± 12.07%. The average release flux ( F ) was 1624.58 ± 2064.5 μg/m 2 , and the average release rate ( V ) was 361.33 ± 465.31 ng/(m 2 ·s). Within the 100-m atmospheric boundary layer, the total NH 3 flux that was released subsequently during the evaporation of all snowfall events in Changchun during the study period was 46.97 mg/m 2 . The average release flux for individual snowfall events was 688.66 μg/m 2 , which constituted approximately 2.44% of the NH 3 concentration documented in the winter atmosphere of Changchun. During the snow evaporation or sublimation process, R was positively correlated with the environmental temperature ( P