Preparation and study of straw porous biochar with aromatic ring structure for adsorption performance and mechanism toward TNT red water

• Published in: Environmental science and pollution research international 2023-12, Vol.30 (56), p.118483-118494
• Main Authors: Liu, Nengsheng, Qin, Jiangzhou, Ge, Xinrui, Lu, Yanyu, Zhang, Jihan, Zhao, Quanlin, Ye, Zhengfang
• Format: Article
• Language: English
• Subjects: 2,4,6-Trinitrotoluene; acetone; Adsorption; Aquatic Pollution; Aromatic compounds; Atmospheric Protection/Air Quality Control/Air Pollution; biochar; carbon; Charcoal; Charcoal - chemistry; Chemical oxygen demand; Chemical reactions; Chemical synthesis; Data analysis; Earth and Environmental Science; Ecotoxicology; Environment; Environmental Chemistry; Environmental Health; Ethanol; hydrothermal carbonization; Kinetics; Oryza; Porosity; Research Article; rice; Rice straw; Ring structures; sorption isotherms; Straw; surface area; toxicity; Trinitrotoluene; Waste Water Technology; Wastewater; Wastewater treatment; Water; Water Management; Water Pollutants, Chemical - chemistry; Water Pollution Control
• ISSN: 1614-7499; 0944-1344; 1614-7499
• DOI: 10.1007/s11356-023-30672-9

2,4,6-Trinitrotoluene (TNT) production processes generate a substantial amount of toxic wastewater. Therefore, it is crucial to identify efficient and sustainable methods for treating this wastewater. This paper explores the application of sustainable biomass-derived carbon produced from rice straw for the adsorption of 2,4,6-trinitrotoluene (TNT) red water. The rice straw–derived biochar (SBC) materials were synthesized by two-step reactions through hydrothermal carbonization and chemical activation with KOH. Characterization of the fabricated biochar was conducted using various techniques. Here, the chemical oxygen demand (COD) was used as an evaluation index for adsorption efficiency. The adsorption kinetics showed a good fit with the pseudo-second-order model, and the adsorption equilibrium was achieved in 30 min. The biochar’s high surface area (1319 m 2 /g) and large pore volume (1.058 cm 3 /g) gave it a large adsorption capacity. The Langmuir model exhibited better correlation for equilibrium data analysis, with a maximum adsorption capacity of 173.9 mg/g at 298 K. The SBC was found to have a high removal effect over a wide pH range (from 1 to 13) and showed remarkable stability after undergoing five desorption-adsorption cycles using ethanol and acetone as eluent. The results provide a simple and low-cost method for the efficient treatment of TNT red water. Graphical abstract