Loading…
Hydrogen Production by Glycerol Steam Reforming on the Ni/CaO-Al2O3 Catalysts: The Study of Synergistic Effect Between CaO and Al2O3
Ni catalysts impregnated on CaO–Al 2 O 3 with various Al/Ca molar ratios were synthesized, and employed in the glycerol steam reforming process to investigate the effect of calcium content on the catalyst efficiency. The prepared catalysts were characterized by XRD, BET, H 2 -TPR, CO 2 -TPD and SEM...
Saved in:
| Published in: | Catalysis letters 2023-12, Vol.153 (12), p.3698-3711 |
|---|---|
| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3 |
| container_end_page | 3711 |
| container_issue | 12 |
| container_start_page | 3698 |
| container_title | Catalysis letters |
| container_volume | 153 |
| creator | Sabokmalek, Saleh Alavi, Seyed Mehdi Rezaei, Mehran Akbari, Ehsan |
| description | Ni catalysts impregnated on CaO–Al
2
O
3
with various Al/Ca molar ratios were synthesized, and employed in the glycerol steam reforming process to investigate the effect of calcium content on the catalyst efficiency. The prepared catalysts were characterized by XRD, BET, H
2
-TPR, CO
2
-TPD and SEM analyses. According to the preliminary tests, the characteristic features of the catalysts were directly affected by the Al/Ca molar ratio. The specific surface area and total pore volume increased with increasing in Al
2
O
3
content. Meanwhile, the higher CaO content increased the catalyst reducibility and also the concentration of basic sites. The sample with Al/Ca of 2 had the best performance with glycerol conversion of 99.4% and H
2
yield of 99.9% at 700 °C. Moreover, the results revealed that the catalyst calcined at 500 °C, and reduced at 700 °C possessed a glycerol conversion of 99.4% and this catalyst was selected as the best sample among the studied catalysts.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-022-04247-1 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3153572428</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3153572428</sourcerecordid><originalsourceid>FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3</originalsourceid><addsrcrecordid>eNp9kU1LAzEQhhdRsFb_gKeAFy9r87EfXW-11FYoVmyF3kKanV23bDeaZJG9-8MdW0Hw4CEkMM_7ZmbeILhk9IZRmg4co3HCQ8rxRDxKQ3YU9Fic8nCYZutjfFPGQpHy9Wlw5tyWUpqlLOsFn7Mut6aEhjxZk7faV6Yhm45M606DNTVZelA78gyFsbuqKQmW_SuQx2owVotwVPOFIGPlVd05727JCmtL3-YdMQVZdg3YsnK-0mRSFKA9uQP_AfgbiolqcrI3OA9OClU7uPi5-8HL_WQ1noXzxfRhPJqHWsTchzyJMkaHOskUG7I4Aq4jjSPnSmWJToBTwWIllI5BMwa0EDgw1VykaSQ2mRb94Prg-2bNewvOy13lNNS1asC0TqJc4M4iPkT06g-6Na1tsDvJcaVRTBFDih8obY1zFgr5Zqudsp1kVH4HIw_BSOxS7oORDEXiIHIINyXYX-t_VF80O45K</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2879450242</pqid></control><display><type>article</type><title>Hydrogen Production by Glycerol Steam Reforming on the Ni/CaO-Al2O3 Catalysts: The Study of Synergistic Effect Between CaO and Al2O3</title><source>Springer Link</source><creator>Sabokmalek, Saleh ; Alavi, Seyed Mehdi ; Rezaei, Mehran ; Akbari, Ehsan</creator><creatorcontrib>Sabokmalek, Saleh ; Alavi, Seyed Mehdi ; Rezaei, Mehran ; Akbari, Ehsan</creatorcontrib><description>Ni catalysts impregnated on CaO–Al
2
O
3
with various Al/Ca molar ratios were synthesized, and employed in the glycerol steam reforming process to investigate the effect of calcium content on the catalyst efficiency. The prepared catalysts were characterized by XRD, BET, H
2
-TPR, CO
2
-TPD and SEM analyses. According to the preliminary tests, the characteristic features of the catalysts were directly affected by the Al/Ca molar ratio. The specific surface area and total pore volume increased with increasing in Al
2
O
3
content. Meanwhile, the higher CaO content increased the catalyst reducibility and also the concentration of basic sites. The sample with Al/Ca of 2 had the best performance with glycerol conversion of 99.4% and H
2
yield of 99.9% at 700 °C. Moreover, the results revealed that the catalyst calcined at 500 °C, and reduced at 700 °C possessed a glycerol conversion of 99.4% and this catalyst was selected as the best sample among the studied catalysts.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-022-04247-1</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum oxide ; calcium ; Calcium oxide ; Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Conversion ; Glycerol ; Hydrogen production ; Industrial Chemistry/Chemical Engineering ; Organometallic Chemistry ; Physical Chemistry ; Reforming ; steam ; surface area ; synergism ; Synergistic effect</subject><ispartof>Catalysis letters, 2023-12, Vol.153 (12), p.3698-3711</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3</citedby><cites>FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Sabokmalek, Saleh</creatorcontrib><creatorcontrib>Alavi, Seyed Mehdi</creatorcontrib><creatorcontrib>Rezaei, Mehran</creatorcontrib><creatorcontrib>Akbari, Ehsan</creatorcontrib><title>Hydrogen Production by Glycerol Steam Reforming on the Ni/CaO-Al2O3 Catalysts: The Study of Synergistic Effect Between CaO and Al2O3</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Ni catalysts impregnated on CaO–Al
2
O
3
with various Al/Ca molar ratios were synthesized, and employed in the glycerol steam reforming process to investigate the effect of calcium content on the catalyst efficiency. The prepared catalysts were characterized by XRD, BET, H
2
-TPR, CO
2
-TPD and SEM analyses. According to the preliminary tests, the characteristic features of the catalysts were directly affected by the Al/Ca molar ratio. The specific surface area and total pore volume increased with increasing in Al
2
O
3
content. Meanwhile, the higher CaO content increased the catalyst reducibility and also the concentration of basic sites. The sample with Al/Ca of 2 had the best performance with glycerol conversion of 99.4% and H
2
yield of 99.9% at 700 °C. Moreover, the results revealed that the catalyst calcined at 500 °C, and reduced at 700 °C possessed a glycerol conversion of 99.4% and this catalyst was selected as the best sample among the studied catalysts.
Graphical Abstract</description><subject>Aluminum oxide</subject><subject>calcium</subject><subject>Calcium oxide</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Conversion</subject><subject>Glycerol</subject><subject>Hydrogen production</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><subject>Reforming</subject><subject>steam</subject><subject>surface area</subject><subject>synergism</subject><subject>Synergistic effect</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kU1LAzEQhhdRsFb_gKeAFy9r87EfXW-11FYoVmyF3kKanV23bDeaZJG9-8MdW0Hw4CEkMM_7ZmbeILhk9IZRmg4co3HCQ8rxRDxKQ3YU9Fic8nCYZutjfFPGQpHy9Wlw5tyWUpqlLOsFn7Mut6aEhjxZk7faV6Yhm45M606DNTVZelA78gyFsbuqKQmW_SuQx2owVotwVPOFIGPlVd05727JCmtL3-YdMQVZdg3YsnK-0mRSFKA9uQP_AfgbiolqcrI3OA9OClU7uPi5-8HL_WQ1noXzxfRhPJqHWsTchzyJMkaHOskUG7I4Aq4jjSPnSmWJToBTwWIllI5BMwa0EDgw1VykaSQ2mRb94Prg-2bNewvOy13lNNS1asC0TqJc4M4iPkT06g-6Na1tsDvJcaVRTBFDih8obY1zFgr5Zqudsp1kVH4HIw_BSOxS7oORDEXiIHIINyXYX-t_VF80O45K</recordid><startdate>20231201</startdate><enddate>20231201</enddate><creator>Sabokmalek, Saleh</creator><creator>Alavi, Seyed Mehdi</creator><creator>Rezaei, Mehran</creator><creator>Akbari, Ehsan</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20231201</creationdate><title>Hydrogen Production by Glycerol Steam Reforming on the Ni/CaO-Al2O3 Catalysts: The Study of Synergistic Effect Between CaO and Al2O3</title><author>Sabokmalek, Saleh ; Alavi, Seyed Mehdi ; Rezaei, Mehran ; Akbari, Ehsan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aluminum oxide</topic><topic>calcium</topic><topic>Calcium oxide</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Conversion</topic><topic>Glycerol</topic><topic>Hydrogen production</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><topic>Reforming</topic><topic>steam</topic><topic>surface area</topic><topic>synergism</topic><topic>Synergistic effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sabokmalek, Saleh</creatorcontrib><creatorcontrib>Alavi, Seyed Mehdi</creatorcontrib><creatorcontrib>Rezaei, Mehran</creatorcontrib><creatorcontrib>Akbari, Ehsan</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sabokmalek, Saleh</au><au>Alavi, Seyed Mehdi</au><au>Rezaei, Mehran</au><au>Akbari, Ehsan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hydrogen Production by Glycerol Steam Reforming on the Ni/CaO-Al2O3 Catalysts: The Study of Synergistic Effect Between CaO and Al2O3</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2023-12-01</date><risdate>2023</risdate><volume>153</volume><issue>12</issue><spage>3698</spage><epage>3711</epage><pages>3698-3711</pages><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Ni catalysts impregnated on CaO–Al
2
O
3
with various Al/Ca molar ratios were synthesized, and employed in the glycerol steam reforming process to investigate the effect of calcium content on the catalyst efficiency. The prepared catalysts were characterized by XRD, BET, H
2
-TPR, CO
2
-TPD and SEM analyses. According to the preliminary tests, the characteristic features of the catalysts were directly affected by the Al/Ca molar ratio. The specific surface area and total pore volume increased with increasing in Al
2
O
3
content. Meanwhile, the higher CaO content increased the catalyst reducibility and also the concentration of basic sites. The sample with Al/Ca of 2 had the best performance with glycerol conversion of 99.4% and H
2
yield of 99.9% at 700 °C. Moreover, the results revealed that the catalyst calcined at 500 °C, and reduced at 700 °C possessed a glycerol conversion of 99.4% and this catalyst was selected as the best sample among the studied catalysts.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-022-04247-1</doi><tpages>14</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2023-12, Vol.153 (12), p.3698-3711 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3153572428 |
| source | Springer Link |
| subjects | Aluminum oxide calcium Calcium oxide Catalysis Catalysts Chemistry Chemistry and Materials Science Conversion Glycerol Hydrogen production Industrial Chemistry/Chemical Engineering Organometallic Chemistry Physical Chemistry Reforming steam surface area synergism Synergistic effect |
| title | Hydrogen Production by Glycerol Steam Reforming on the Ni/CaO-Al2O3 Catalysts: The Study of Synergistic Effect Between CaO and Al2O3 |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T02%3A06%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hydrogen%20Production%20by%20Glycerol%20Steam%20Reforming%20on%20the%20Ni/CaO-Al2O3%20Catalysts:%20The%20Study%20of%20Synergistic%20Effect%20Between%20CaO%20and%20Al2O3&rft.jtitle=Catalysis%20letters&rft.au=Sabokmalek,%20Saleh&rft.date=2023-12-01&rft.volume=153&rft.issue=12&rft.spage=3698&rft.epage=3711&rft.pages=3698-3711&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-022-04247-1&rft_dat=%3Cproquest_cross%3E3153572428%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c352t-2649108c69a18154e2c4c022daa96c6e20315a3ac5ec11e0f33720c237743b9c3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2879450242&rft_id=info:pmid/&rfr_iscdi=true |