Waste-derived catalysts for tar cracking in hot syngas cleaning

• Published in: Waste management (Elmsford) 2024-04, Vol.179, p.163-174
• Main Authors: Parrillo, Francesco, Ardolino, Filomena, Boccia, Carmine, Arconati, Vincenzo, Ruoppolo, Giovanna, Arena, Umberto
• Format: Article
• Language: English
• Subjects: catalysts; catalytic activity; energy; gasification; hydrogen; iron; naphthalene; oxidation; sewage sludge; species; steam; Syngas cleaning; synthesis gas; Tar cracking; Waste gasification; waste management; Waste-derived catalysts
• ISSN: 0956-053X; 1879-2456
• DOI: 10.1016/j.wasman.2024.03.006

[Display omitted] •Naphthalene is efficiently converted by red mud and sewage sludge ashes in long-term tests.•The support allows to prevent catalysts loss and metal sintering.•Reduced iron is more active than its oxidised form.•Alkali and Alkaline Earth Metals play an important role by hindering coke deposition.•Steam helps to limit coke deposition, while partially oxidising the iron sites. Catalytic tar cracking is a promising technique for hot syngas cleaning unit in gasification plants because it can preserve tars chemical energy, so increasing the syngas heating value. The cost associated with catalyst preparation is a key issue, together with its deactivation induced by coke deposition. Iron is a cheap and frequently used catalyst, which can also be found in some industrial wastes. The study aims to assess the catalytic efficiency for tar cracking of two waste-derived materials (red mud and sewage sludge) having high content of iron. The catalysts were supported on spheres of γ-Al2O3, and their efficiency was compared to that of a pure iron catalyst. The role of support was investigated by testing pure red mud, with and without the support. A series of long-term tests using naphthalene as tar model compound were carried out under different values of process temperatures (750 °C-800 °C) and steam concentrations (0 %-7.5 %). The waste derived catalysts showed lower hydrogen yields compared to pure iron catalyst, due to their lower content of iron. On the other hand, the conversion efficiencies of all the tested catalysts resulted rather similar, since the Alkali and Alkaline-Earth Metallic species present on the surface of waste-derived catalyst help in preventing coke deposition. The iron oxidation state appears to play an important role, with reduced iron more active than its oxidised form in the tar cracking reactions. This indicates the importance of tuning steam concentration to keep constant the reduced state of iron while limiting coke deposition.