Epitaxial growth of Bi4Ti3O12-BiPO4 Z-scheme heterojunction to promote carrier transfer for photocatalytic oxidation of NO

• Published in: Journal of colloid and interface science 2024-12, Vol.675, p.721-730
• Main Authors: Liu, Zhinian, Li, Guojun, Zhang, Mingjia, Zhang, Chen, Zheng, Wangsheng, You, Xiangting, Zhang, Shule, Zhong, Qin
• Format: Article
• Language: English
• Subjects: adsorption; Bi4Ti3O12-BiPO4 heterojunction; electric field; Epitaxial growth; nanosheets; NO photo-oxidation; oxidation; photocatalysis; photocatalysts; redox potential; Z-scheme
• ISSN: 0021-9797; 1095-7103; 1095-7103
• DOI: 10.1016/j.jcis.2024.07.069

[Display omitted] The lack of compactness in heterojunction interfaces and poor charge separation is a great challenge in developing high-efficiency heterojunction photocatalysts. Herein, a novel Bi4Ti3O12-BiPO4 heterojunction was successfully prepared for the first time by epitaxial growth of BiPO4 on the surface of Bi4Ti3O12 nanosheets. The optimized Bi4Ti3O12-BiPO4-0.5 increased the NO oxidation efficiency to 73.05%, surpassing pure Bi4Ti3O12 (63.45%) and BiPO4 (8.35%). Experiments and theoretical calculations indicated that the closely contacted heterointerface between BTO and BPO promoted the generation of the built-in electric field, which led to the formation of the Z- scheme transfer pathway for the photogenerated carriers. Therefore, the separation of photogenerated carriers was facilitated while retaining high redox potential, generating more ·O2– and ·OH to participate in NO oxidation. Furthermore, the adsorption of NO and O2 was enhanced by introducing BiPO4, further improving the photocatalytic NO oxidation performance. This work emphasizes the critical role of heterointerface in accelerating charge transfer, providing a basis for the design and construction of tightly contacted heterojunction photocatalysts.