Effect of Solvent on the Rate of Ozonolysis: Development of a Homogeneous Flow Ozonolysis Protocol

Herein, we describe the effect of organic solvents on ozone solubility and the rate of ozonolysis reactions using rapid injection NMR spectroscopy. The tabulated solubility and kinetic data allowed for the design of a homogeneous ozonolysis flow reactor capable of delivering precise quantities of di...

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Bibliographic Details
Published in:Journal of organic chemistry 2023-10, Vol.88 (19), p.13720-13726
Main Authors: Arriaga, Danniel K., Kang, Seokmin, Thomas, Andy A.
Format: Article
Language:English
Subjects:
nuclear magnetic resonance spectroscopy
olefin
organic chemistry
ozone
ozonolysis
solubility
solvents
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Summary:Herein, we describe the effect of organic solvents on ozone solubility and the rate of ozonolysis reactions using rapid injection NMR spectroscopy. The tabulated solubility and kinetic data allowed for the design of a homogeneous ozonolysis flow reactor capable of delivering precise quantities of dissolved ozone to various olefin substrates.
ISSN:0022-3263
1520-6904
DOI:10.1021/acs.joc.3c01372