Enhancing Oxygen Activation Ability by Composite Interface Construction over a 2D Co3O4‑Based Monolithic Catalyst for Toluene Oxidation

• Published in: Environmental science & technology 2024-08, Vol.58 (33), p.14906-14917
• Main Authors: Li, Rong, Huang, Yu, Zhu, Yimai, Guo, Mingzhi, Peng, Wei, Zhi, Yizhou, Wang, Liqin, Cao, Junji, Lee, Shuncheng
• Format: Article
• Language: English
• Subjects: Catalysts; catalytic activity; Catalytic converters; Chemisorption; Cobalt oxides; Composite materials; Construction sites; foams; Heat treatment; Interfaces; Intermediates; Iron oxides; Metal foams; Metal oxides; Molten salts; Organic compounds; Oxidation; Oxygen; Physico-Chemical Treatment and Resource Recovery; pollution; Reaction intermediates; Scanning transmission electron microscopy; technology; temperature; Toluene; Transmission electron microscopy; VOCs; Volatile organic compounds
• ISSN: 0013-936X; 1520-5851; 1520-5851
• DOI: 10.1021/acs.est.4c04157

Developing robust metal-based monolithic catalysts with efficient oxygen activation capacity is crucial for thermal catalytic treatment of volatile organic compound (VOC) pollution. Two-dimensional (2D) metal oxides are alternative thermal catalysts, but their traditional loading strategies on carriers still face challenges in practical applications. Herein, we propose a novel in situ molten salt-loading strategy that synchronously enables the construction of 2D Co3O4 and its growth on Fe foam for the first time to yield a unique monolithic catalyst named Co3O4/Fe–S. Compared to the Co3O4 nanocube-loaded Fe foam, Co3O4/Fe–S exhibits a significantly improved catalytic performance with a temperature reduction of 44 °C at 90% toluene conversion. Aberration-corrected scanning transmission electron microscopy and theoretical calculation suggest that Co3O4/Fe–S possesses abundant 2D Co3O4/Fe3O4 composite interfaces, which promote the construction of active sites (oxygen vacancy and Co3+) to boost oxygen activation and toluene chemisorption, thereby accelerating the transformation of reaction intermediates through Langmuir–Hinshelwood (L-H) and Mars–van Krevelen (MvK) mechanisms. Moreover, the growth mechanism reveals that 2D Co3O4/Fe3O4 composite interfaces are generated in situ in molten salt, inducing the growth of 2D Co3O4 onto the surface lattice of 2D Fe3O4. This study provides new insights into enhancing oxygen activation and opens an unprecedented avenue in preparing efficient monolithic catalysts for VOC oxidation.