Advanced applications of hydroxyapatite nanocomposite materials for heavy metals and organic pollutants removal by adsorption and photocatalytic degradation: A review

• Published in: Chemosphere (Oxford) 2024-06, Vol.358, p.142236-142236, Article 142236
• Main Authors: Miyah, Youssef, El Messaoudi, Noureddine, Benjelloun, Mohammed, Acikbas, Yaser, Şenol, Zeynep Mine, Ciğeroğlu, Zeynep, Lopez-Maldonado, Eduardo Alberto
• Format: Article
• Language: English
• Subjects: Adsorption; Catalysis; Durapatite - chemistry; Heavy metals; hydrogen; hydroxyapatite; Hydroxyapatite nanocomposite; Metals, Heavy - chemistry; nanocomposites; Nanocomposites - chemistry; Organic pollutants; photocatalysis; Photocatalytic degradation; surface area; Water Pollutants, Chemical - analysis; Water Pollutants, Chemical - chemistry; Water Purification - methods
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2024.142236

This comprehensive review delves into the forefront of scientific exploration, focusing on hydroxyapatite-based nanocomposites (HANCs) and their transformative role in the adsorption of heavy metals (HMs) and organic pollutants (OPs). Nanoscale properties, including high surface area and porous structure, contribute to the enhanced adsorption capabilities of HANCs. The nanocomposites' reactive sites facilitate efficient contaminant interactions, resulting in improved kinetics and capacities. HANCs exhibit selective adsorption properties, showcasing the ability to discriminate between different contaminants. The eco-friendly synthesis methods and potential for recyclability position the HANCs as environmentally friendly solutions for adsorption processes. The review acknowledges the dynamic nature of the field, which is characterized by continuous innovation and a robust focus on ongoing research endeavors. The paper highlights the HANCs' selective adsorption capabilities of various HMs and OPs through various interactions, including hydrogen and electrostatic bonding. These materials are also used for aquatic pollutants' photocatalytic degradation, where reactive hydroxyl radicals are generated to oxidize organic pollutants quickly. Future perspectives explore novel compositions, fabrication methods, and applications, driving the evolution of HANCs for improved adsorption performance. This review provides a comprehensive synthesis of the state-of-the-art HANCs, offering insights into their diverse applications, sustainability aspects, and pivotal role in advancing adsorption technologies for HMs and OPs. [Display omitted] •Mechanisms for enhancing the properties of HANCs.•Feasibility of adsorption and photocatalytic degradation of HMs and OPs with HANCs.•Analyzes various HANC materials used till date for HM and OP removal.•The HANC exhibits unusually high selectivity for HMs and OPs.