Effect of thermo-oxidative aging on thermal elongation performance of XLPE insulation for high-voltage cables

• Published in: Polymer degradation and stability 2023-04, Vol.210, p.110291, Article 110291
• Main Authors: Liu, Hongjian, Wang, Shihang, Li, Shengtao, Wu, Yifan, Jiang, Liuhao, Lang, Jianyu, Yuan, Jialiang, Liu, Jiajun
• Format: Article
• Language: English
• Subjects: air; Antioxidant; crosslinking; degradation; gels; insulating materials; Insulation; nitrogen; oxidation; polyethylene; Power cable; synergism; Thermal elongation; Thermo-oxidative aging; X-ray diffraction; XLPE
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2023.110291

•Crosslinked network and antioxidation performance of the crosslinked polyethylene insulation materials jointly determine their thermal elongation performance.•Permanent elongation of crosslinked polyethylene has a stronger correlation with the gel content of the sample after thermal elongation test.•The higher the efficiency of antioxidant, the smaller the thermal elongation of crosslinked polyethylene.•The thermal elongation test under nitrogen atmosphere is more suitable for high-voltage cable insulation test. The thermal elongation of cross-linked polyethylene (XLPE) insulation for high-voltage cables is an important factor for evaluating the high-temperature mechanical performance, which is an important parameter included in the testing standards of the power cable insulation. Previous studies have found that the thermal elongation of XLPE insulation for high-voltage cable depends on the cross-linking degree, but have not dealt with the effect of the thermo-oxidative aging during the thermal elongation test. In this paper, the thermal elongation experiments of the XLPE samples compounded with different kinds of antioxidants were carried out under both air and nitrogen atmospheres. The molecular structure changes of the XLPE samples after thermal elongation under air atmosphere were examined by gel content, FTIR spectra and X-ray diffraction. The oxidation induction periods were also measured to analyze the antioxidation performance of the phenolic antioxidants and study its contribution to the thermal elongation performance. The results showed that the XLPE samples underwent thermo-oxidative aging in the thermal elongation test under air atmosphere at 200 °C. It caused that the thermal elongation properties can not accurately reflect the cross-linking degree of the original XLPE samples, but has a strong correlation with the gel content of the aged samples. Antioxidants can inhibit the thermo-oxidative aging effect on the network structure, leading to a slower uptrend of elongation under the air atmosphere. This indicates that the thermal elongation performance of XLPE insulation is determined by the synergistic effect of the network structure and the antioxidation performance, and this can provide reference significance for optimizing the evaluation methods of high-voltage cable XLPE insulation performance.