Electrochemical promoted C H bond chlorination of sulfoxonium ylides

The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providing a green and mil...

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Published in:Tetrahedron letters 2023-01, Vol.114, p.154244, Article 154244
Main Authors: Zhang, Li-Ming, Fu, Zi-Hao, Yuan, Da-Fu, Guo, Ming-Zhong, Li, Ming, Wen, Li-Rong, Zhang, Lin-Bao
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Language:English
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chlorination
chlorine
electrochemistry
electrolytes
magnesium chloride
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cited_by cdi_FETCH-LOGICAL-c284t-25994ee2acf58ffa02969b52cd6a9357d6d9513b42d5cdd9d60e2ab20ecc07ab3
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container_title Tetrahedron letters
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description The first electrochemical promoted CH bond chlorination of sulfoxonium ylides was accomplished using magnesium chloride as the chlorine source, as well as a supporting electrolyte. This method does not require transition metal catalysts, external oxidants, and electrolytes, providing a green and mild route for the functionalization of sulfoxonium ylides.
doi_str_mv 10.1016/j.tetlet.2022.154244
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subjects chlorination
chlorine
electrochemistry
electrolytes
magnesium chloride
title Electrochemical promoted C H bond chlorination of sulfoxonium ylides
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