Enhanced photocatalytic performance of colored Ti2O3–Ti3O5–TiO2 heterostructure for the degradation of antibiotic ofloxacin and bactericidal effect

• Published in: Chemosphere (Oxford) 2024-10, Vol.365, p.143247, Article 143247
• Main Authors: Figueroa-Torres, M.Z., Meneses-Rodríguez, David, Obregón, Sergio, Cano, Arely, Vázquez, Alejandro, Hernández-Adame, Luis, Ruiz-Gómez, Miguel A.
• Format: Article
• Language: English
• Subjects: absorption; antibacterial properties; antibiotics; Emergent contaminants; Escherichia coli; hydroxyl radicals; light; lighting; ofloxacin; oxidation; Photocatalysis; photolysis; Reactive oxygen species; remediation; Simulated solar light; solar radiation; Staphylococcus aureus; superoxide anion
• ISSN: 0045-6535; 1879-1298; 1879-1298
• DOI: 10.1016/j.chemosphere.2024.143247

Removing emergent contaminants, such as pharmaceuticals, and inhibiting bacteria by photocatalysis represents an interesting alternative for water remediation. We report the effective preparation of colored powders containing Ti2O3, Ti3O5, and TiO2, by a simple thermal oxidation reaction of a Ti2O3 precursor from 400 °C to 800 °C. The material obtained at 500 °C (P500 sample) exhibited the highest photocatalytic performance under simulated solar light, reaching 54% degradation of antibiotic ofloxacin and a bacteria inactivation of 51% and 62% for Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus), respectively. The superoxide anion radical was the main specie contributing to the photodegradation of ofloxacin, while the hydroxyl radical showed negligible effect. A synergy between the physicochemical properties of the phases in the P500 sample contributes to the electrons transfer, visible light absorption capability and generation of reactive oxygen species, resulting in its remarkable photoactivity. The comparison in terms of surface-specific activity revealed that the P500 sample is more efficient than commercially available TiO2 P25. This fact opens the option of using commercially available Ti2O3 and TiO2 P25 to obtain composites for promoting photoinduced reactions using natural solar light. [Display omitted] •Colored powders are very photoactive under simulated sunlight irradiation.•Ti3+ surface species promote the formation of superoxide anion radical.•P500 showed better efficiency in terms of surface-specific activity than TiO2 P25.•Potential applications of these colored powders under natural solar illumination.