Adding colour to ion-selective membranes

• Published in: Talanta (Oxford) 2025-05, Vol.286, p.127497, Article 127497
• Main Authors: Buczyńska, Dorota, Stelmach, Emilia, Jankowska, Maria, Ruszczyńska, Anna, Piątek, Piotr, Maksymiuk, Krzysztof, Michalska, Agata
• Format: Article
• Language: English
• Subjects: Ion-exchanger; Ion-selective membranes; Nile blue; Optode; Potentiometry
• ISSN: 0039-9140; 1873-3573; 1873-3573
• DOI: 10.1016/j.talanta.2024.127497

An idea of using ion-exchanger salt containing optically active cations to prepare ion-selective membranes is proposed. Although the presence of an ion-exchanger in the composition of neutral ionophore based sensors is necessary, the choice of available salts for cation-selective sensors preparation, is usually limited to sodium or potassium compounds. In this work we propose application of an alternative salt, using a cation optically active both in absorption and emission mode as a mobile one. Thus, coloured ion-selective membranes can be obtained. This in turn opens new possibilities of monitoring the state of the receptor layer as well as allows direct analytical application of ion-selective membranes in simple optical mode with all benefits related to eliminating the necessity of using reference electrodes. As a model system Nile blue derivative of tetrakis[3,5-bis(trifluoromethyl)phenyl]borate ion-exchanger was prepared and used to obtain potassium or calcium selective sensors. Selective exchange of ions between the membrane and solution, leading to an increase in optical signal of the solution, can be used to quantify the presence of analyte ions. Thus the sensor pretreatment process is becoming a source of analytical information. The applicability of this approach was verified in determining the presence of potassium ions in the vast majority of interfering ions, e.g. present as impurities in the reagent grade calcium chloride. The resulting potassium ions contents was well comparable with values obtained in course of ICP-MS approach. [Display omitted] •Novel type of ion-exchanger for ion-selective membranes have been proposed.•Optical activity of used compound allows analytical use of sensors conditioning process.•For solutions containing vast excess of interfering ions, conditioning allows quantification of primary ions.•Results obtained using herein proposed ion-exchanger are well comparable with those from ICP-MS based approach.