Loading…
Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction
Known for its exceptional light-absorbing properties, conjugated organic molecule are capable of efficiently converting solar energy into chemical energy, providing a new avenue for the utilization of renewable energy. In this work, we successfully synthesized and designed a conjugated organic molec...
Saved in:
| Published in: | Catalysis letters 2025-02, Vol.155 (2), p.75-75, Article 75 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | |
|---|---|
| cites | cdi_FETCH-LOGICAL-c233t-715b43126935c616983aef450d711640459bfa9d35c595f8d2cf231da0b3ee653 |
| container_end_page | 75 |
| container_issue | 2 |
| container_start_page | 75 |
| container_title | Catalysis letters |
| container_volume | 155 |
| creator | Pan, Yumin Xie, Tingting Peng, Jiming Cao, Cuihui Zou, Bi-Qun |
| description | Known for its exceptional light-absorbing properties, conjugated organic molecule are capable of efficiently converting solar energy into chemical energy, providing a new avenue for the utilization of renewable energy. In this work, we successfully synthesized and designed a conjugated organic molecule with 4,7-di(9
H
-carbazol-9-yl)benzo[
c
][1,2,5]thiadiazole (
B2Cz
). In trifluoromethylation reactions,
B2Cz
exhibits unique activity by activating C–H bonds to selectively introduce trifluoromethyl groups. Furthermore,
B2Cz
acts as a photo-cocatalyst alongside NiBr
2
in C–N coupling reactions, which demonstrated excellent synergistic catalytic effects. This catalytic system not only enhances reaction efficiency but also significantly advances environmental friendliness and sustainability.
Graphical Abstract |
| doi_str_mv | 10.1007/s10562-024-04900-x |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_3165876064</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3165876064</sourcerecordid><originalsourceid>FETCH-LOGICAL-c233t-715b43126935c616983aef450d711640459bfa9d35c595f8d2cf231da0b3ee653</originalsourceid><addsrcrecordid>eNp9kc2KFDEUhQtRcBx9AVcBN25Kb5JKUllKM_7A6Aw6A7ML6VTSnSadtElKpne-gy_gs_kkpqeVAReu7oX7nXMPnK57juEVBhCvCwbGSQ9k6GGQAP3tg-4EM0H6Ucibh20HjHsqyM3j7kkpGwCQAsuT7ud1_GZ98HGF6tqiL_vYRvUGXaZqY_U6oOTQIsXNvNLVTugir3Rs948pWDMHi3RBZ8554xuOLteppt7oqsP-4HKVvQtzymlr63ofdPUpIh2nv2C6Rxe_vv_41D7Nu7s0n602B_pp98jpUOyzP_O0u357drV4359fvPuweHPeG0Jp7QVmy4FiwiVlhmMuR6qtGxhMAmM-wMDk0mk5tSuTzI0TMY5QPGlYUms5o6fdy6PvLqevsy1VbX0xNgQdbZqLopizUXDgQ0Nf_INu0pxjS9cohimMUpBGkSNlciolW6d22W913isM6lCaOpamWmnqrjR120T0KCoNjiub763_o_oN_N2eKw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3151308972</pqid></control><display><type>article</type><title>Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction</title><source>Springer Link</source><creator>Pan, Yumin ; Xie, Tingting ; Peng, Jiming ; Cao, Cuihui ; Zou, Bi-Qun</creator><creatorcontrib>Pan, Yumin ; Xie, Tingting ; Peng, Jiming ; Cao, Cuihui ; Zou, Bi-Qun</creatorcontrib><description>Known for its exceptional light-absorbing properties, conjugated organic molecule are capable of efficiently converting solar energy into chemical energy, providing a new avenue for the utilization of renewable energy. In this work, we successfully synthesized and designed a conjugated organic molecule with 4,7-di(9
H
-carbazol-9-yl)benzo[
c
][1,2,5]thiadiazole (
B2Cz
). In trifluoromethylation reactions,
B2Cz
exhibits unique activity by activating C–H bonds to selectively introduce trifluoromethyl groups. Furthermore,
B2Cz
acts as a photo-cocatalyst alongside NiBr
2
in C–N coupling reactions, which demonstrated excellent synergistic catalytic effects. This catalytic system not only enhances reaction efficiency but also significantly advances environmental friendliness and sustainability.
Graphical Abstract</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-024-04900-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alternative energy sources ; Catalysis ; Catalytic converters ; Chemical energy ; Chemical reactions ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coupling ; Electromagnetic absorption ; energy ; Free radicals ; Hydrocarbons ; Industrial Chemistry/Chemical Engineering ; Light ; Organic chemistry ; organic compounds ; Organometallic Chemistry ; Oxidation ; Photocatalysis ; Physical Chemistry ; Renewable resources ; Solar energy ; Solar energy conversion ; Thiadiazoles</subject><ispartof>Catalysis letters, 2025-02, Vol.155 (2), p.75-75, Article 75</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2024 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>Copyright Springer Nature B.V. Feb 2025</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c233t-715b43126935c616983aef450d711640459bfa9d35c595f8d2cf231da0b3ee653</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Pan, Yumin</creatorcontrib><creatorcontrib>Xie, Tingting</creatorcontrib><creatorcontrib>Peng, Jiming</creatorcontrib><creatorcontrib>Cao, Cuihui</creatorcontrib><creatorcontrib>Zou, Bi-Qun</creatorcontrib><title>Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>Known for its exceptional light-absorbing properties, conjugated organic molecule are capable of efficiently converting solar energy into chemical energy, providing a new avenue for the utilization of renewable energy. In this work, we successfully synthesized and designed a conjugated organic molecule with 4,7-di(9
H
-carbazol-9-yl)benzo[
c
][1,2,5]thiadiazole (
B2Cz
). In trifluoromethylation reactions,
B2Cz
exhibits unique activity by activating C–H bonds to selectively introduce trifluoromethyl groups. Furthermore,
B2Cz
acts as a photo-cocatalyst alongside NiBr
2
in C–N coupling reactions, which demonstrated excellent synergistic catalytic effects. This catalytic system not only enhances reaction efficiency but also significantly advances environmental friendliness and sustainability.
Graphical Abstract</description><subject>Alternative energy sources</subject><subject>Catalysis</subject><subject>Catalytic converters</subject><subject>Chemical energy</subject><subject>Chemical reactions</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coupling</subject><subject>Electromagnetic absorption</subject><subject>energy</subject><subject>Free radicals</subject><subject>Hydrocarbons</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Light</subject><subject>Organic chemistry</subject><subject>organic compounds</subject><subject>Organometallic Chemistry</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Physical Chemistry</subject><subject>Renewable resources</subject><subject>Solar energy</subject><subject>Solar energy conversion</subject><subject>Thiadiazoles</subject><issn>1011-372X</issn><issn>1572-879X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2025</creationdate><recordtype>article</recordtype><recordid>eNp9kc2KFDEUhQtRcBx9AVcBN25Kb5JKUllKM_7A6Aw6A7ML6VTSnSadtElKpne-gy_gs_kkpqeVAReu7oX7nXMPnK57juEVBhCvCwbGSQ9k6GGQAP3tg-4EM0H6Ucibh20HjHsqyM3j7kkpGwCQAsuT7ud1_GZ98HGF6tqiL_vYRvUGXaZqY_U6oOTQIsXNvNLVTugir3Rs948pWDMHi3RBZ8554xuOLteppt7oqsP-4HKVvQtzymlr63ofdPUpIh2nv2C6Rxe_vv_41D7Nu7s0n602B_pp98jpUOyzP_O0u357drV4359fvPuweHPeG0Jp7QVmy4FiwiVlhmMuR6qtGxhMAmM-wMDk0mk5tSuTzI0TMY5QPGlYUms5o6fdy6PvLqevsy1VbX0xNgQdbZqLopizUXDgQ0Nf_INu0pxjS9cohimMUpBGkSNlciolW6d22W913isM6lCaOpamWmnqrjR120T0KCoNjiub763_o_oN_N2eKw</recordid><startdate>20250201</startdate><enddate>20250201</enddate><creator>Pan, Yumin</creator><creator>Xie, Tingting</creator><creator>Peng, Jiming</creator><creator>Cao, Cuihui</creator><creator>Zou, Bi-Qun</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20250201</creationdate><title>Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction</title><author>Pan, Yumin ; Xie, Tingting ; Peng, Jiming ; Cao, Cuihui ; Zou, Bi-Qun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c233t-715b43126935c616983aef450d711640459bfa9d35c595f8d2cf231da0b3ee653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2025</creationdate><topic>Alternative energy sources</topic><topic>Catalysis</topic><topic>Catalytic converters</topic><topic>Chemical energy</topic><topic>Chemical reactions</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coupling</topic><topic>Electromagnetic absorption</topic><topic>energy</topic><topic>Free radicals</topic><topic>Hydrocarbons</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Light</topic><topic>Organic chemistry</topic><topic>organic compounds</topic><topic>Organometallic Chemistry</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Physical Chemistry</topic><topic>Renewable resources</topic><topic>Solar energy</topic><topic>Solar energy conversion</topic><topic>Thiadiazoles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pan, Yumin</creatorcontrib><creatorcontrib>Xie, Tingting</creatorcontrib><creatorcontrib>Peng, Jiming</creatorcontrib><creatorcontrib>Cao, Cuihui</creatorcontrib><creatorcontrib>Zou, Bi-Qun</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Catalysis letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pan, Yumin</au><au>Xie, Tingting</au><au>Peng, Jiming</au><au>Cao, Cuihui</au><au>Zou, Bi-Qun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction</atitle><jtitle>Catalysis letters</jtitle><stitle>Catal Lett</stitle><date>2025-02-01</date><risdate>2025</risdate><volume>155</volume><issue>2</issue><spage>75</spage><epage>75</epage><pages>75-75</pages><artnum>75</artnum><issn>1011-372X</issn><eissn>1572-879X</eissn><abstract>Known for its exceptional light-absorbing properties, conjugated organic molecule are capable of efficiently converting solar energy into chemical energy, providing a new avenue for the utilization of renewable energy. In this work, we successfully synthesized and designed a conjugated organic molecule with 4,7-di(9
H
-carbazol-9-yl)benzo[
c
][1,2,5]thiadiazole (
B2Cz
). In trifluoromethylation reactions,
B2Cz
exhibits unique activity by activating C–H bonds to selectively introduce trifluoromethyl groups. Furthermore,
B2Cz
acts as a photo-cocatalyst alongside NiBr
2
in C–N coupling reactions, which demonstrated excellent synergistic catalytic effects. This catalytic system not only enhances reaction efficiency but also significantly advances environmental friendliness and sustainability.
Graphical Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-024-04900-x</doi><tpages>1</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1011-372X |
| ispartof | Catalysis letters, 2025-02, Vol.155 (2), p.75-75, Article 75 |
| issn | 1011-372X 1572-879X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_3165876064 |
| source | Springer Link |
| subjects | Alternative energy sources Catalysis Catalytic converters Chemical energy Chemical reactions Chemical synthesis Chemistry Chemistry and Materials Science Coupling Electromagnetic absorption energy Free radicals Hydrocarbons Industrial Chemistry/Chemical Engineering Light Organic chemistry organic compounds Organometallic Chemistry Oxidation Photocatalysis Physical Chemistry Renewable resources Solar energy Solar energy conversion Thiadiazoles |
| title | Unveiling the Synthetic Potential of Conjugated Organic Molecule as Efficient Photo-catalytic Trifluoromethylation and Photo-cocatalytic C–N Coupling Reaction |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-22T12%3A09%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Unveiling%20the%20Synthetic%20Potential%20of%20Conjugated%20Organic%20Molecule%20as%20Efficient%20Photo-catalytic%20Trifluoromethylation%20and%20Photo-cocatalytic%20C%E2%80%93N%20Coupling%20Reaction&rft.jtitle=Catalysis%20letters&rft.au=Pan,%20Yumin&rft.date=2025-02-01&rft.volume=155&rft.issue=2&rft.spage=75&rft.epage=75&rft.pages=75-75&rft.artnum=75&rft.issn=1011-372X&rft.eissn=1572-879X&rft_id=info:doi/10.1007/s10562-024-04900-x&rft_dat=%3Cproquest_cross%3E3165876064%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c233t-715b43126935c616983aef450d711640459bfa9d35c595f8d2cf231da0b3ee653%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3151308972&rft_id=info:pmid/&rfr_iscdi=true |