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Enhanced Potential of Amorphous Electrode Materials: Case Study of RuO2

Amorphous nanosized RuO2 obtained electrochemically as well as by a solution route exhibits a higher potential (580 mV) compared with the bulk crystal value. The results here show that a cell voltage that involves amorphous constituents can be i) reliably studied, ii) quantitatively understood in te...

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2008-02, Vol.20 (3), p.501-505
Main Authors: Delmer, O., Balaya, P., Kienle, L., Maier, J.
Format: Article
Language:English
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Summary:Amorphous nanosized RuO2 obtained electrochemically as well as by a solution route exhibits a higher potential (580 mV) compared with the bulk crystal value. The results here show that a cell voltage that involves amorphous constituents can be i) reliably studied, ii) quantitatively understood in terms of a loss of long‐range order, and iii) be used to achieve a higher potential in Li batteries, in this case more than half a volt.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.200701349