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The Peltier effect
Thermodynamic consideration of thermoelectricity in metals was applied to the Peltier effect, like it was done recently for the Seebeck effect. The Peltier coefficient was derived from the difference in the total energy of electrons in two metals in contact: Π=ɛ 0 T ln(1+ T Θ V ), where ɛ 0 is the ‘...
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Published in: | Journal of thermal analysis and calorimetry 2008, Vol.91 (1), p.311-315 |
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Main Author: | |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Thermodynamic consideration of thermoelectricity in metals was applied to the Peltier effect, like it was done recently for the Seebeck effect. The Peltier coefficient was derived from the difference in the total energy of electrons in two metals in contact: Π=ɛ
0
T
ln(1+
T
Θ
V
), where ɛ
0
is the ‘universal’ sensitivity of thermocouples and Θ
V
is the characteristic temperature of a particular thermocouple.
The Peltier and Seebeck coefficients derived from the new thermodynamic model were shown not to hold the Thomson relation exactly, but only in the low-temperature limit. |
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ISSN: | 1388-6150 1588-2926 1572-8943 |
DOI: | 10.1007/s10973-007-8336-9 |