Hairy particle-supported 4-N,N-dialkylaminopyridine: An efficient and recyclable nucleophilic organocatalyst

A polymer brush‐supported 4‐N,N‐dialkylaminopyridine catalyst was prepared by surface‐initiated nitroxide‐mediated polymerization from initiator functionalized crosslinked polystyrene particles. The hairy particles efficiently catalyzed the acylation of secondary alcohols and Baylis‐Hillman reaction...

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Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2008-05, Vol.46 (10), p.3438-3446
Main Authors: Zhao, Bin, Jiang, Xiaoming, Li, Dejin, Jiang, Xueguang, O'Lenick, Thomas G, Li, Bing, Li, Christopher Y
Format: Article
Language:English
Subjects:
Applied sciences
catalysis
catalysts
Exact sciences and technology
living polymerization
Organic polymers
Physicochemistry of polymers
Properties and characterization
radical polymerization
Special properties (catalyst, reagent or carrier)
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cited_by cdi_FETCH-LOGICAL-c4621-58c398ffa0f25e2fdd3ac3fcae7cc52e1f78978d7d13e7c91184156a7571eef3
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container_issue 10
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container_title Journal of polymer science. Part A, Polymer chemistry
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creator Zhao, Bin
Jiang, Xiaoming
Li, Dejin
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O'Lenick, Thomas G
Li, Bing
Li, Christopher Y
description A polymer brush‐supported 4‐N,N‐dialkylaminopyridine catalyst was prepared by surface‐initiated nitroxide‐mediated polymerization from initiator functionalized crosslinked polystyrene particles. The hairy particles efficiently catalyzed the acylation of secondary alcohols and Baylis‐Hillman reaction of 4‐nitrobenzaldehyde and methyl vinyl ketone, and were recycled at least six times with no or negligible decrease in the reaction yield.
doi_str_mv 10.1002/pola.22681
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subjects Applied sciences
catalysis
catalysts
Exact sciences and technology
living polymerization
Organic polymers
Physicochemistry of polymers
Properties and characterization
radical polymerization
Special properties (catalyst, reagent or carrier)
title Hairy particle-supported 4-N,N-dialkylaminopyridine: An efficient and recyclable nucleophilic organocatalyst
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