Removal of Cr(VI) from aqueous solutions using pre-consumer processing agricultural waste: A case study of rice husk

• Published in: Journal of hazardous materials 2009-02, Vol.162 (1), p.312-320
• Main Authors: Bansal, Manjeet, Garg, Umesh, Singh, Diwan, Garg, V.K.
• Format: Article
• Language: English
• Subjects: Adsorption; Agriculture; Agriculture, rearing and food industries wastes; Applied sciences; Chemical engineering; Chromium Compounds - chemistry; Chromium Compounds - isolation & purification; Chromium(VI); Exact sciences and technology; Formaldehyde - chemistry; FTIR; General purification processes; Hydrogen-Ion Concentration; Industrial Waste - analysis; Microscopy, Electron, Scanning; Oryza - chemistry; Oryza sativa; Pollution; Rice husk; Seeds - chemistry; SEM; Solutions; Spectroscopy, Fourier Transform Infrared; Surface Properties; Thermodynamics; Waste Disposal, Fluid; Wastes; Wastewaters; Water; Water treatment and pollution
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2008.05.037

This paper reports the feasibility of using pre-consumer processing agricultural waste to remove Cr(VI) from synthetic wastewater under different experimental conditions. For this, rice husk, has been used after pre-treatments (boiling and formaldehyde treatment). Effect of various process parameters, namely, pH, adsorbent dose, initial chromium concentration and contact time has been studied in batch systems. The removal of chromium was dependent on the physico-chemical characteristics of the adsorbent, adsorbate concentration and other studied process parameters. Maximum metal removal was observed at pH 2.0. The efficiencies of boiled and formaldehyde treated rice husk for Cr(VI) removal were 71.0% and 76.5% respectively for dilute solutions at 20 g l −1 adsorbent dose. The experimental data were analyzed using Freundlich, Langmuir and Dubinin–Radushkevich (D–R) isotherm models. It was found that Freundlich and D–R models fitted well. The results revealed that the hexavalent chromium is considerably adsorbed on rice husk and it could be an economical method for the removal of hexavalent chromium from aqueous systems. FTIR and SEM were recorded, before and after adsorption, to explore number and position of the functional groups available for Cr(VI) binding on to studied adsorbents and changes in adsorbent surface morphology.