Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis

Hydrogenolysis of organolithium reagents is described under heterogeneous catalysis in the presence of Pd 0. This approach gives details about the H–H bond polarization in the presence of transition metal catalysts. ▪ Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the...

Full description

Saved in:
Bibliographic Details
Published in:Applied catalysis. A, General General, 2008-08, Vol.346 (1), p.86-89
Main Authors: Faucher, Nicolas, Cintrat, Jean-Christophe, Rousseau, Bernard
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Deuterium
Exact sciences and technology
General and physical chemistry
Heterogeneous catalysis
Hydrogenolysis
Organolithium
Palladium
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3
cites cdi_FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3
container_end_page 89
container_issue 1
container_start_page 86
container_title Applied catalysis. A, General
container_volume 346
creator Faucher, Nicolas
Cintrat, Jean-Christophe
Rousseau, Bernard
description Hydrogenolysis of organolithium reagents is described under heterogeneous catalysis in the presence of Pd 0. This approach gives details about the H–H bond polarization in the presence of transition metal catalysts. ▪ Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the first time under heterogeneous catalysis. This work establishes that the carbon–lithium bond can undergo a facile reduction reaction when catalyzed by palladium or platinum catalysts and provides strong evidence for the existence of Pd δ−–H δ+ species.
doi_str_mv 10.1016/j.apcata.2008.05.011
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_32928131</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0926860X0800313X</els_id><sourcerecordid>32928131</sourcerecordid><originalsourceid>FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3</originalsourceid><addsrcrecordid>eNp9kMFO3DAQhq2KSiy0b8Ahl_aWME7WjsMBqUItICGKBEjtyZq1x-BViFPbu9XeeAfesE9CVot6ZC4zh--f0XyMHXGoOHB5vKxwNJixqgFUBaICzj-wGVdtUzaqFXtsBl0tSyXh1z47SGkJAPW8EzN2c0GZYug32ZsCTfZrzD4MRXDF48bG8EBD8YDppLimvwWtvaXBUOFCLG7H7Rj_Pb_8Xk3sGPIjJZ8-sY8O-0Sf3_ohu__x_e7sorz6eX559u2qNI1sc8nrZq4coGvdAhdIgCRROY4kOkJjqRFzCSTVhFirnOysFO1USqBdGGoO2dfd3jGGPytKWT_5ZKjvcaCwSrqpu1rxhk_gfAeaGFKK5PQY_RPGjeagt_r0Uu_06a0-DUJP-qbYl7f9mAz2LuJgfPqfrUEIxSVM3OmOo-nZtaeok_FbM9ZHMlnb4N8_9AoM7YqR</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>32928131</pqid></control><display><type>article</type><title>Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis</title><source>ScienceDirect Journals</source><creator>Faucher, Nicolas ; Cintrat, Jean-Christophe ; Rousseau, Bernard</creator><creatorcontrib>Faucher, Nicolas ; Cintrat, Jean-Christophe ; Rousseau, Bernard</creatorcontrib><description>Hydrogenolysis of organolithium reagents is described under heterogeneous catalysis in the presence of Pd 0. This approach gives details about the H–H bond polarization in the presence of transition metal catalysts. ▪ Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the first time under heterogeneous catalysis. This work establishes that the carbon–lithium bond can undergo a facile reduction reaction when catalyzed by palladium or platinum catalysts and provides strong evidence for the existence of Pd δ−–H δ+ species.</description><identifier>ISSN: 0926-860X</identifier><identifier>EISSN: 1873-3875</identifier><identifier>DOI: 10.1016/j.apcata.2008.05.011</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Catalysis ; Chemistry ; Deuterium ; Exact sciences and technology ; General and physical chemistry ; Heterogeneous catalysis ; Hydrogenolysis ; Organolithium ; Palladium ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Applied catalysis. A, General, 2008-08, Vol.346 (1), p.86-89</ispartof><rights>2008 Elsevier B.V.</rights><rights>2008 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3</citedby><cites>FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=20558160$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Faucher, Nicolas</creatorcontrib><creatorcontrib>Cintrat, Jean-Christophe</creatorcontrib><creatorcontrib>Rousseau, Bernard</creatorcontrib><title>Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis</title><title>Applied catalysis. A, General</title><description>Hydrogenolysis of organolithium reagents is described under heterogeneous catalysis in the presence of Pd 0. This approach gives details about the H–H bond polarization in the presence of transition metal catalysts. ▪ Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the first time under heterogeneous catalysis. This work establishes that the carbon–lithium bond can undergo a facile reduction reaction when catalyzed by palladium or platinum catalysts and provides strong evidence for the existence of Pd δ−–H δ+ species.</description><subject>Catalysis</subject><subject>Chemistry</subject><subject>Deuterium</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Heterogeneous catalysis</subject><subject>Hydrogenolysis</subject><subject>Organolithium</subject><subject>Palladium</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>0926-860X</issn><issn>1873-3875</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kMFO3DAQhq2KSiy0b8Ahl_aWME7WjsMBqUItICGKBEjtyZq1x-BViFPbu9XeeAfesE9CVot6ZC4zh--f0XyMHXGoOHB5vKxwNJixqgFUBaICzj-wGVdtUzaqFXtsBl0tSyXh1z47SGkJAPW8EzN2c0GZYug32ZsCTfZrzD4MRXDF48bG8EBD8YDppLimvwWtvaXBUOFCLG7H7Rj_Pb_8Xk3sGPIjJZ8-sY8O-0Sf3_ohu__x_e7sorz6eX559u2qNI1sc8nrZq4coGvdAhdIgCRROY4kOkJjqRFzCSTVhFirnOysFO1USqBdGGoO2dfd3jGGPytKWT_5ZKjvcaCwSrqpu1rxhk_gfAeaGFKK5PQY_RPGjeagt_r0Uu_06a0-DUJP-qbYl7f9mAz2LuJgfPqfrUEIxSVM3OmOo-nZtaeok_FbM9ZHMlnb4N8_9AoM7YqR</recordid><startdate>20080831</startdate><enddate>20080831</enddate><creator>Faucher, Nicolas</creator><creator>Cintrat, Jean-Christophe</creator><creator>Rousseau, Bernard</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20080831</creationdate><title>Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis</title><author>Faucher, Nicolas ; Cintrat, Jean-Christophe ; Rousseau, Bernard</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Catalysis</topic><topic>Chemistry</topic><topic>Deuterium</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Heterogeneous catalysis</topic><topic>Hydrogenolysis</topic><topic>Organolithium</topic><topic>Palladium</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Faucher, Nicolas</creatorcontrib><creatorcontrib>Cintrat, Jean-Christophe</creatorcontrib><creatorcontrib>Rousseau, Bernard</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. A, General</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Faucher, Nicolas</au><au>Cintrat, Jean-Christophe</au><au>Rousseau, Bernard</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis</atitle><jtitle>Applied catalysis. A, General</jtitle><date>2008-08-31</date><risdate>2008</risdate><volume>346</volume><issue>1</issue><spage>86</spage><epage>89</epage><pages>86-89</pages><issn>0926-860X</issn><eissn>1873-3875</eissn><abstract>Hydrogenolysis of organolithium reagents is described under heterogeneous catalysis in the presence of Pd 0. This approach gives details about the H–H bond polarization in the presence of transition metal catalysts. ▪ Hydrogenolysis or deuterogenolysis of organolithium compounds is described for the first time under heterogeneous catalysis. This work establishes that the carbon–lithium bond can undergo a facile reduction reaction when catalyzed by palladium or platinum catalysts and provides strong evidence for the existence of Pd δ−–H δ+ species.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apcata.2008.05.011</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0926-860X
ispartof Applied catalysis. A, General, 2008-08, Vol.346 (1), p.86-89
issn 0926-860X
1873-3875
language eng
recordid cdi_proquest_miscellaneous_32928131
source ScienceDirect Journals
subjects Catalysis
Chemistry
Deuterium
Exact sciences and technology
General and physical chemistry
Heterogeneous catalysis
Hydrogenolysis
Organolithium
Palladium
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title Heterolytic activation of hydrogen gas: New evidence for Spencer–Yu hypothesis
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T18%3A01%3A54IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Heterolytic%20activation%20of%20hydrogen%20gas:%20New%20evidence%20for%20Spencer%E2%80%93Yu%20hypothesis&rft.jtitle=Applied%20catalysis.%20A,%20General&rft.au=Faucher,%20Nicolas&rft.date=2008-08-31&rft.volume=346&rft.issue=1&rft.spage=86&rft.epage=89&rft.pages=86-89&rft.issn=0926-860X&rft.eissn=1873-3875&rft_id=info:doi/10.1016/j.apcata.2008.05.011&rft_dat=%3Cproquest_cross%3E32928131%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c367t-12348f0af7fbabae0ae6a8f1ae59eacde35460e680afdd8f69d65777785adbce3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=32928131&rft_id=info:pmid/&rfr_iscdi=true