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Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines
Two co-crystals of individual isomers of higher fullerenes C 76 -D 2 and C 78 (2)-C 2v with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C 78 (2) as well a...
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Published in: | Fullerenes, nanotubes, and carbon nanostructures nanotubes, and carbon nanostructures, 2009-01, Vol.17 (1), p.67-77 |
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container_title | Fullerenes, nanotubes, and carbon nanostructures |
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creator | Epple, L. Amsharov, K. Yu Jansen, M. |
description | Two co-crystals of individual isomers of higher fullerenes C
76
-D
2
and C
78
(2)-C
2v
with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C
78
(2) as well as its bond ordering have been confirmed crystallographically for the first time. It was demonstrated that metalloporphyrines may serve as a universal co-crystal agent able to orientationally fix pristine higher fullerenes in the crystal lattice. |
doi_str_mv | 10.1080/15363830802519420 |
format | article |
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76
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2
and C
78
(2)-C
2v
with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C
78
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76
-D
2
and C
78
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2v
with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C
78
(2) as well as its bond ordering have been confirmed crystallographically for the first time. It was demonstrated that metalloporphyrines may serve as a universal co-crystal agent able to orientationally fix pristine higher fullerenes in the crystal lattice.</description><subject>higher fullerenes</subject><subject>porphyrine</subject><subject>single crystal structure</subject><subject>X-ray</subject><issn>1536-383X</issn><issn>1536-4046</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkT1PwzAQhiMEEqXwA9g8IRgC_ogTV2KpwkcrITEAEltknEtj5NrFdoCO_HOM2q0D0726e95XurssOyX4kmCBrwhnJRMsScrJpKB4Lxv99fICF-X-Vifg9TA7CuEdYyKoYKPs5yn6QcXBQ0CuQ7EHNLet_tTtIA2a6UUPHt0NxoAHm2bBLcEHVFdlfkORtG2S4pxe5DX9RNqi2im_DlGagL507NF0kW-oIUfPEL1c9WDXZuX8ql97bSEcZwddwuFkW8fZy93tcz3LHx7v5_X0IdeUVDFnb-WkYJJVwITglSgEkxVwDG2Zdmux4AoIrd5KxRlUKlFKUKUKwTnvug7YODvb5K68-xggxGapgwJjpAU3hIbRSVlQUiaw2oDads4v5Zfzpm2iXBvnOy-t0qHZOXcTv2NyXv_rZAQ3fx_bjWC_IQuHeA</recordid><startdate>20090101</startdate><enddate>20090101</enddate><creator>Epple, L.</creator><creator>Amsharov, K. Yu</creator><creator>Jansen, M.</creator><general>Taylor & Francis Group, LLC</general><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20090101</creationdate><title>Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines</title><author>Epple, L. ; Amsharov, K. Yu ; Jansen, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i217t-3b6943a37e388578483a7e50ed6153d085ce127b6c53e7ce38c82cc48555fffe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>higher fullerenes</topic><topic>porphyrine</topic><topic>single crystal structure</topic><topic>X-ray</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Epple, L.</creatorcontrib><creatorcontrib>Amsharov, K. Yu</creatorcontrib><creatorcontrib>Jansen, M.</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Fullerenes, nanotubes, and carbon nanostructures</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Epple, L.</au><au>Amsharov, K. Yu</au><au>Jansen, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines</atitle><jtitle>Fullerenes, nanotubes, and carbon nanostructures</jtitle><date>2009-01-01</date><risdate>2009</risdate><volume>17</volume><issue>1</issue><spage>67</spage><epage>77</epage><pages>67-77</pages><issn>1536-383X</issn><eissn>1536-4046</eissn><abstract>Two co-crystals of individual isomers of higher fullerenes C
76
-D
2
and C
78
(2)-C
2v
with Ag- and Cu-tetraphenylporphyrines were obtained using the temperature difference crystal growth technique and investigated by means of single crystal X-ray analysis. The C-C connectivity of C
78
(2) as well as its bond ordering have been confirmed crystallographically for the first time. It was demonstrated that metalloporphyrines may serve as a universal co-crystal agent able to orientationally fix pristine higher fullerenes in the crystal lattice.</abstract><pub>Taylor & Francis Group, LLC</pub><doi>10.1080/15363830802519420</doi><tpages>11</tpages></addata></record> |
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subjects | higher fullerenes porphyrine single crystal structure X-ray |
title | Structures of the Individual Higher Fullerene Isomers C76-D2 and C78(2)-C2v in Cocrystals with Ag- and Cu- Tetraphenylporphyrines |
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