Evaluation of aluminum dross waste as raw material for refractories

• Published in: Ceramics international 2008-04, Vol.34 (3), p.581-591
• Main Authors: Yoshimura, H.N., Abreu, A.P., Molisani, A.L., de Camargo, A.C., Portela, J.C.S., Narita, N.E.
• Format: Article
• Language: English
• Subjects: Applied sciences; B. Microstructure-final; Building materials. Ceramics. Glasses; C. Strength; Chemical industry and chemicals; E. Refractories; Exact sciences and technology; Indexing in process; Other wastes and particular components of wastes; Pollution; Q1; Recycling; Refractory products; Wastes
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2006.12.007

An aluminum dross waste from plasma processing for Al metal reclamation was tested as a replacement raw material in refractories. The main phases of the starting Al dross waste material were MgAl 2O 4 and AlN. The waste was tested to replace calcined alumina in castables and refractory clay in a molded refractory at levels below 6.5%. The results of physical and mechanical tests indicated that the waste may be applied directly, without prior calcination, as a substitute for fine structural components in refractories. The waste and water contents used in processing, however, must be optimized to avoid the formation of crack-like defects in the microstructure. The origin of these defects is related to the generation of gas from the waste at high temperatures. It is not known if these crack defects impact physical properties. The waste was also tested as a replacement for anti-oxidant elements (Al and Si powders) in a resin-bonded refractory. Oxidation tests, however, indicated a negative effect on oxidation resistance.