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Electrodeposition of ZnO nanorods in the presence of metal ions

We report on structural and optical changes induced by impurity incorporation in ZnO nanorods grown via electrodeposition. We find the lattice parameters of the hexagonal ZnO rods to be larger than in defect-free single-crystalline ZnO. SIMS measurements indicate impurity incorporation and doping in...

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Bibliographic Details
Published in:Materials letters 2009-04, Vol.63 (9), p.736-738
Main Authors: Seipel, Bjoern, Nadarajah, Athavan, Wutzke, Ben, Könenkamp, Rolf
Format: Article
Language:English
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Summary:We report on structural and optical changes induced by impurity incorporation in ZnO nanorods grown via electrodeposition. We find the lattice parameters of the hexagonal ZnO rods to be larger than in defect-free single-crystalline ZnO. SIMS measurements indicate impurity incorporation and doping in the bulk of the nanorods. The impurity content correlates with changes in the electroluminescence spectra. The maximum of the defect luminescence band around 600 nm shifts towards longer wavelengths with metal incorporation. Aluminum incorporation leads to a narrow luminescence band close by the bandgap of ZnO around 390 nm.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2008.12.037