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Heterogeneous base catalyzed synthesis of 2-oxazolidinones/2-imidiazolidinones via transesterification of ethylene carbonate with β-aminoalcohols/1,2-diamines
Several heterogeneous basic metal oxide catalysts were screened for the synthesis of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines. Among the several catalysts screened, MgO was found to be the best catalyst, as...
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| Published in: | Applied catalysis. A, General General, 2008-06, Vol.341 (1), p.133-138 |
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| Main Authors: | , , , , |
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| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c252t-e4d7c51b29066b083ddb8e07f7b07dba2f5669a8105dbe2ff545a74f2cad41fb3 |
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| cites | cdi_FETCH-LOGICAL-c252t-e4d7c51b29066b083ddb8e07f7b07dba2f5669a8105dbe2ff545a74f2cad41fb3 |
| container_end_page | 138 |
| container_issue | 1 |
| container_start_page | 133 |
| container_title | Applied catalysis. A, General |
| container_volume | 341 |
| creator | Jagtap, Sachin R. Patil, Yogesh P. Fujita, Shin-Ichiro Arai, Masahiko Bhanage, Bhalchandra M. |
| description | Several heterogeneous basic metal oxide catalysts were screened for the synthesis of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines. Among the several catalysts screened, MgO was found to be the best catalyst, as it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalysts at 80
°C within 6
h in ethanol. Basic properties of the metal oxide catalysts were compared using temperature programmed desorption (TPD) studies with CO
2. The relationship between the catalyst performance and the basic property of each catalyst has been discussed.
Syntheses of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines using several basic metal oxides were studied. The basic properties of the various metal oxide catalysts were compared using TPD studies with CO
2. Among the several catalysts screened, MgO was found to be best catalyst, for it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalyst at 80
°C within 6
h in ethanol.
▪ |
| doi_str_mv | 10.1016/j.apcata.2008.02.035 |
| format | article |
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°C within 6
h in ethanol. Basic properties of the metal oxide catalysts were compared using temperature programmed desorption (TPD) studies with CO
2. The relationship between the catalyst performance and the basic property of each catalyst has been discussed.
Syntheses of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines using several basic metal oxides were studied. The basic properties of the various metal oxide catalysts were compared using TPD studies with CO
2. Among the several catalysts screened, MgO was found to be best catalyst, for it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalyst at 80
°C within 6
h in ethanol.
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°C within 6
h in ethanol. Basic properties of the metal oxide catalysts were compared using temperature programmed desorption (TPD) studies with CO
2. The relationship between the catalyst performance and the basic property of each catalyst has been discussed.
Syntheses of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines using several basic metal oxides were studied. The basic properties of the various metal oxide catalysts were compared using TPD studies with CO
2. Among the several catalysts screened, MgO was found to be best catalyst, for it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalyst at 80
°C within 6
h in ethanol.
▪</description><subject>Basic metal oxide</subject><subject>Ethylene carbonate</subject><subject>Heterogeneous catalysis</subject><subject>Imidiazolidinones</subject><subject>Oxazolidinones</subject><issn>0926-860X</issn><issn>1873-3875</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp9kUtuFDEQhi0EEkPIDbLoFSvcU7a73d0bJBQBiRSJTSKxs_woMx71tAfbCUwuwx04CGfCk2HBilWpSvV_9fgJuWDQMmByvW313uqiWw4wtsBbEP0zsmLjIKgYh_45WcHEJR0lfHlJXuW8BQDeTf2K_LzCgil-xQXjfW6MztgcUfPhEV2TD0vZYA65ib7hNP7Qj3EOLixxwbzmNOxq8m-teQi6KUkvGXPlBh8qLMTlqMeyOcx1TuUnExddsPkeyqb5_YvqXZXr2cZNnPOaveW0YmsN82vywus54_nfeEbuPn64vbyiN58_XV--v6GW97xQ7Nxge2b4BFIaGIVzZkQY_GBgcEZz30s56ZFB7wxy7_uu10PnudWuY96IM_LmxN2n-O2-Lq92IVucZ_30GCWEADkJWRu7U6NNMeeEXu1T2Ol0UAzU0Q21VSc31NENBVxVN6rs3UmG9YiHgEllG3Cx6EJCW5SL4f-AP_gzm2Q</recordid><startdate>20080615</startdate><enddate>20080615</enddate><creator>Jagtap, Sachin R.</creator><creator>Patil, Yogesh P.</creator><creator>Fujita, Shin-Ichiro</creator><creator>Arai, Masahiko</creator><creator>Bhanage, Bhalchandra M.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20080615</creationdate><title>Heterogeneous base catalyzed synthesis of 2-oxazolidinones/2-imidiazolidinones via transesterification of ethylene carbonate with β-aminoalcohols/1,2-diamines</title><author>Jagtap, Sachin R. ; Patil, Yogesh P. ; Fujita, Shin-Ichiro ; Arai, Masahiko ; Bhanage, Bhalchandra M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c252t-e4d7c51b29066b083ddb8e07f7b07dba2f5669a8105dbe2ff545a74f2cad41fb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Basic metal oxide</topic><topic>Ethylene carbonate</topic><topic>Heterogeneous catalysis</topic><topic>Imidiazolidinones</topic><topic>Oxazolidinones</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jagtap, Sachin R.</creatorcontrib><creatorcontrib>Patil, Yogesh P.</creatorcontrib><creatorcontrib>Fujita, Shin-Ichiro</creatorcontrib><creatorcontrib>Arai, Masahiko</creatorcontrib><creatorcontrib>Bhanage, Bhalchandra M.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. A, General</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jagtap, Sachin R.</au><au>Patil, Yogesh P.</au><au>Fujita, Shin-Ichiro</au><au>Arai, Masahiko</au><au>Bhanage, Bhalchandra M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Heterogeneous base catalyzed synthesis of 2-oxazolidinones/2-imidiazolidinones via transesterification of ethylene carbonate with β-aminoalcohols/1,2-diamines</atitle><jtitle>Applied catalysis. A, General</jtitle><date>2008-06-15</date><risdate>2008</risdate><volume>341</volume><issue>1</issue><spage>133</spage><epage>138</epage><pages>133-138</pages><issn>0926-860X</issn><eissn>1873-3875</eissn><abstract>Several heterogeneous basic metal oxide catalysts were screened for the synthesis of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines. Among the several catalysts screened, MgO was found to be the best catalyst, as it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalysts at 80
°C within 6
h in ethanol. Basic properties of the metal oxide catalysts were compared using temperature programmed desorption (TPD) studies with CO
2. The relationship between the catalyst performance and the basic property of each catalyst has been discussed.
Syntheses of 2-oxazolidinones and 2-imidiazolidinones via transesterification of ethylene carbonate with different β-aminoalcohols or 1,2-diamines using several basic metal oxides were studied. The basic properties of the various metal oxide catalysts were compared using TPD studies with CO
2. Among the several catalysts screened, MgO was found to be best catalyst, for it has excellent recyclability. Various reaction parameters were studied in detail. Excellent yields of the products were obtained using MgO as catalyst at 80
°C within 6
h in ethanol.
▪</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.apcata.2008.02.035</doi><tpages>6</tpages></addata></record> |
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| ispartof | Applied catalysis. A, General, 2008-06, Vol.341 (1), p.133-138 |
| issn | 0926-860X 1873-3875 |
| language | eng |
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| source | ScienceDirect Journals |
| subjects | Basic metal oxide Ethylene carbonate Heterogeneous catalysis Imidiazolidinones Oxazolidinones |
| title | Heterogeneous base catalyzed synthesis of 2-oxazolidinones/2-imidiazolidinones via transesterification of ethylene carbonate with β-aminoalcohols/1,2-diamines |
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