Blanc Reaction of Aromatic Compounds Catalyzed by Ionic Liquids

Ionic liquids have been used as catalysts for Blanc reaction of toluene. The effects of reaction temperature, reaction time and dosage of the ionic liquid catalyst have been investigated, and the catalytic performance of different ionic liquid catalysts for toluene chloromethylation was also studied...

Full description

Saved in:
Bibliographic Details
Published in:Chinese journal of chemical engineering 2008-06, Vol.16 (3), p.357-360
Main Author: 方岩雄 邓运泉 任清刚 黄敬平 张赛丹 黄宝华 张焜
Format: Article
Language:English
Subjects:
催化作用
氯甲基化反应
离子液体
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Ionic liquids have been used as catalysts for Blanc reaction of toluene. The effects of reaction temperature, reaction time and dosage of the ionic liquid catalyst have been investigated, and the catalytic performance of different ionic liquid catalysts for toluene chloromethylation was also studied. The reaction was found to proceed under mild conditions with excellent conversion （up to 90%） in the absence of Lewis acids. The ionic liquids could be recycled and reused without loss of their catalytic activities.
ISSN:1004-9541
2210-321X
DOI:10.1016/S1004-9541(08)60087-7