Blanc Reaction of Aromatic Compounds Catalyzed by Ionic Liquids

Ionic liquids have been used as catalysts for Blanc reaction of toluene. The effects of reaction temperature, reaction time and dosage of the ionic liquid catalyst have been investigated, and the catalytic performance of different ionic liquid catalysts for toluene chloromethylation was also studied...

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Published in:Chinese journal of chemical engineering 2008-06, Vol.16 (3), p.357-360
Main Author: 方岩雄 邓运泉 任清刚 黄敬平 张赛丹 黄宝华 张焜
Format: Article
Language:English
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催化作用
氯甲基化反应
离子液体
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description Ionic liquids have been used as catalysts for Blanc reaction of toluene. The effects of reaction temperature, reaction time and dosage of the ionic liquid catalyst have been investigated, and the catalytic performance of different ionic liquid catalysts for toluene chloromethylation was also studied. The reaction was found to proceed under mild conditions with excellent conversion （up to 90%） in the absence of Lewis acids. The ionic liquids could be recycled and reused without loss of their catalytic activities.
doi_str_mv 10.1016/S1004-9541(08)60087-7
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subjects 催化作用
氯甲基化反应
离子液体
title Blanc Reaction of Aromatic Compounds Catalyzed by Ionic Liquids
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