Features of mechanism of free radical initiation in polymers under exposure to nitrogen oxides

The mechanism of interactions of NO, NO2, NO3 as well as dimers of NO2 with functional groups of organic molecules and polymers is considered. It is shown that nitrogen oxides are active initiators of radical reactions as a result of which various molecular products of nitration and stable nitrogen‐...

Full description

Saved in:
Bibliographic Details
Published in:Polymers for advanced technologies 2008-06, Vol.19 (6), p.475-484
Main Authors: Davydov, E. Y., Gaponova, I. S., Pokholok, T. V., Vorotnikov, A. P., Pariiskii, G. B., Zaikov, G. E.
Format: Article
Language:English
Subjects:
EPR spectra
macroradicals
mechanism of reactions
nitrogen oxides
polymers
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833
cites cdi_FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833
container_end_page 484
container_issue 6
container_start_page 475
container_title Polymers for advanced technologies
container_volume 19
creator Davydov, E. Y.
Gaponova, I. S.
Pokholok, T. V.
Vorotnikov, A. P.
Pariiskii, G. B.
Zaikov, G. E.
description The mechanism of interactions of NO, NO2, NO3 as well as dimers of NO2 with functional groups of organic molecules and polymers is considered. It is shown that nitrogen oxides are active initiators of radical reactions as a result of which various molecular products of nitration and stable nitrogen‐containing radicals are formed. Features of the initiation mechanism determining the composition of molecular and radical products of conversions of the compounds on exposure to nitrogen oxides have been revealed. Copyright © 2008 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/pat.1094
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_33556742</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>33556742</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833</originalsourceid><addsrcrecordid>eNp10EFLwzAUB_AiCs4p-BFyEi_VJC9t1uMUN4VNh0wED4bYvmq0bWrS4vbtzZgIHjy9_-P9eId_FB0zesYo5eet7kLIxE40CCOLWTJiu5sseCyZkPvRgffvlIZbJgfR8wR11zv0xJakxvxNN8bXm6V0iMTpwuS6IqYxndGdsU2IpLXVukbnSd8U6AiuWuvDD9JZEpyzr9gQuzIF-sNor9SVx6OfOYweJlfLy-t4dje9uRzP4hxAiFhInukUOAeR0IyloyLPWAYSRzkgvNBCZFhCQXXCGKc6lbzgUGopSuAURgDD6GT7t3X2s0ffqdr4HKtKN2h7rwCSJJWCB3i6hbmz3jssVetMrd1aMao2BapQoNoUGGi8pV-mwvW_Ti3Gy7_e-A5Xv167D5VKkIl6vJ2q-YVcTOb3T4rCN9-igMA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>33556742</pqid></control><display><type>article</type><title>Features of mechanism of free radical initiation in polymers under exposure to nitrogen oxides</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Davydov, E. Y. ; Gaponova, I. S. ; Pokholok, T. V. ; Vorotnikov, A. P. ; Pariiskii, G. B. ; Zaikov, G. E.</creator><creatorcontrib>Davydov, E. Y. ; Gaponova, I. S. ; Pokholok, T. V. ; Vorotnikov, A. P. ; Pariiskii, G. B. ; Zaikov, G. E.</creatorcontrib><description>The mechanism of interactions of NO, NO2, NO3 as well as dimers of NO2 with functional groups of organic molecules and polymers is considered. It is shown that nitrogen oxides are active initiators of radical reactions as a result of which various molecular products of nitration and stable nitrogen‐containing radicals are formed. Features of the initiation mechanism determining the composition of molecular and radical products of conversions of the compounds on exposure to nitrogen oxides have been revealed. Copyright © 2008 John Wiley &amp; Sons, Ltd.</description><identifier>ISSN: 1042-7147</identifier><identifier>EISSN: 1099-1581</identifier><identifier>DOI: 10.1002/pat.1094</identifier><language>eng</language><publisher>Chichester, UK: John Wiley &amp; Sons, Ltd</publisher><subject>EPR spectra ; macroradicals ; mechanism of reactions ; nitrogen oxides ; polymers</subject><ispartof>Polymers for advanced technologies, 2008-06, Vol.19 (6), p.475-484</ispartof><rights>Copyright © 2008 John Wiley &amp; Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833</citedby><cites>FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Davydov, E. Y.</creatorcontrib><creatorcontrib>Gaponova, I. S.</creatorcontrib><creatorcontrib>Pokholok, T. V.</creatorcontrib><creatorcontrib>Vorotnikov, A. P.</creatorcontrib><creatorcontrib>Pariiskii, G. B.</creatorcontrib><creatorcontrib>Zaikov, G. E.</creatorcontrib><title>Features of mechanism of free radical initiation in polymers under exposure to nitrogen oxides</title><title>Polymers for advanced technologies</title><addtitle>Polym. Adv. Technol</addtitle><description>The mechanism of interactions of NO, NO2, NO3 as well as dimers of NO2 with functional groups of organic molecules and polymers is considered. It is shown that nitrogen oxides are active initiators of radical reactions as a result of which various molecular products of nitration and stable nitrogen‐containing radicals are formed. Features of the initiation mechanism determining the composition of molecular and radical products of conversions of the compounds on exposure to nitrogen oxides have been revealed. Copyright © 2008 John Wiley &amp; Sons, Ltd.</description><subject>EPR spectra</subject><subject>macroradicals</subject><subject>mechanism of reactions</subject><subject>nitrogen oxides</subject><subject>polymers</subject><issn>1042-7147</issn><issn>1099-1581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNp10EFLwzAUB_AiCs4p-BFyEi_VJC9t1uMUN4VNh0wED4bYvmq0bWrS4vbtzZgIHjy9_-P9eId_FB0zesYo5eet7kLIxE40CCOLWTJiu5sseCyZkPvRgffvlIZbJgfR8wR11zv0xJakxvxNN8bXm6V0iMTpwuS6IqYxndGdsU2IpLXVukbnSd8U6AiuWuvDD9JZEpyzr9gQuzIF-sNor9SVx6OfOYweJlfLy-t4dje9uRzP4hxAiFhInukUOAeR0IyloyLPWAYSRzkgvNBCZFhCQXXCGKc6lbzgUGopSuAURgDD6GT7t3X2s0ffqdr4HKtKN2h7rwCSJJWCB3i6hbmz3jssVetMrd1aMao2BapQoNoUGGi8pV-mwvW_Ti3Gy7_e-A5Xv167D5VKkIl6vJ2q-YVcTOb3T4rCN9-igMA</recordid><startdate>200806</startdate><enddate>200806</enddate><creator>Davydov, E. Y.</creator><creator>Gaponova, I. S.</creator><creator>Pokholok, T. V.</creator><creator>Vorotnikov, A. P.</creator><creator>Pariiskii, G. B.</creator><creator>Zaikov, G. E.</creator><general>John Wiley &amp; Sons, Ltd</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>200806</creationdate><title>Features of mechanism of free radical initiation in polymers under exposure to nitrogen oxides</title><author>Davydov, E. Y. ; Gaponova, I. S. ; Pokholok, T. V. ; Vorotnikov, A. P. ; Pariiskii, G. B. ; Zaikov, G. E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>EPR spectra</topic><topic>macroradicals</topic><topic>mechanism of reactions</topic><topic>nitrogen oxides</topic><topic>polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Davydov, E. Y.</creatorcontrib><creatorcontrib>Gaponova, I. S.</creatorcontrib><creatorcontrib>Pokholok, T. V.</creatorcontrib><creatorcontrib>Vorotnikov, A. P.</creatorcontrib><creatorcontrib>Pariiskii, G. B.</creatorcontrib><creatorcontrib>Zaikov, G. E.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymers for advanced technologies</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Davydov, E. Y.</au><au>Gaponova, I. S.</au><au>Pokholok, T. V.</au><au>Vorotnikov, A. P.</au><au>Pariiskii, G. B.</au><au>Zaikov, G. E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Features of mechanism of free radical initiation in polymers under exposure to nitrogen oxides</atitle><jtitle>Polymers for advanced technologies</jtitle><addtitle>Polym. Adv. Technol</addtitle><date>2008-06</date><risdate>2008</risdate><volume>19</volume><issue>6</issue><spage>475</spage><epage>484</epage><pages>475-484</pages><issn>1042-7147</issn><eissn>1099-1581</eissn><abstract>The mechanism of interactions of NO, NO2, NO3 as well as dimers of NO2 with functional groups of organic molecules and polymers is considered. It is shown that nitrogen oxides are active initiators of radical reactions as a result of which various molecular products of nitration and stable nitrogen‐containing radicals are formed. Features of the initiation mechanism determining the composition of molecular and radical products of conversions of the compounds on exposure to nitrogen oxides have been revealed. Copyright © 2008 John Wiley &amp; Sons, Ltd.</abstract><cop>Chichester, UK</cop><pub>John Wiley &amp; Sons, Ltd</pub><doi>10.1002/pat.1094</doi><tpages>10</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1042-7147
ispartof Polymers for advanced technologies, 2008-06, Vol.19 (6), p.475-484
issn 1042-7147
1099-1581
language eng
recordid cdi_proquest_miscellaneous_33556742
source Wiley-Blackwell Read & Publish Collection
subjects EPR spectra
macroradicals
mechanism of reactions
nitrogen oxides
polymers
title Features of mechanism of free radical initiation in polymers under exposure to nitrogen oxides
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T06%3A35%3A16IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Features%20of%20mechanism%20of%20free%20radical%20initiation%20in%20polymers%20under%20exposure%20to%20nitrogen%20oxides&rft.jtitle=Polymers%20for%20advanced%20technologies&rft.au=Davydov,%20E.%20Y.&rft.date=2008-06&rft.volume=19&rft.issue=6&rft.spage=475&rft.epage=484&rft.pages=475-484&rft.issn=1042-7147&rft.eissn=1099-1581&rft_id=info:doi/10.1002/pat.1094&rft_dat=%3Cproquest_cross%3E33556742%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3344-4729a632234509168dc91937e8c3e3b0d49ef3d0a51120a672d23fa74f3203833%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=33556742&rft_id=info:pmid/&rfr_iscdi=true