Proton conduction of Ba6Mn24O48 tunnel manganite

A protonated Ba6Mn24O48 phase with an original tunnel crystal structure and mixed-valent manganese has been prepared in the form of powders and millimeter-long fibrous crystals (whiskers). A combined study either by impedance spectroscopy or transport measurements revealed that the Ba6Mn24O48 phase...

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Published in:Solid state ionics 2009-03, Vol.180 (2-3), p.187-192
Main Authors: Pomerantseva, E.A., Leonova, L.S., Goodilin, E.A., Dobrovolsky, Yu.A., Tretyakov, Yu.D.
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container_end_page 192
container_issue 2-3
container_start_page 187
container_title Solid state ionics
container_volume 180
creator Pomerantseva, E.A.
Leonova, L.S.
Goodilin, E.A.
Dobrovolsky, Yu.A.
Tretyakov, Yu.D.
description A protonated Ba6Mn24O48 phase with an original tunnel crystal structure and mixed-valent manganese has been prepared in the form of powders and millimeter-long fibrous crystals (whiskers). A combined study either by impedance spectroscopy or transport measurements revealed that the Ba6Mn24O48 phase demonstrates mixed conductivity with both proton and electronic components reaching 10- 3 Omega- 1∙cm- 1 at room temperature.
doi_str_mv 10.1016/j.ssi.2008.11.008
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title Proton conduction of Ba6Mn24O48 tunnel manganite
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