Crystal structure analysis of Bis{(N,N′-dimethylformamide)-[μ-bis-N,N′-(2-oxybenzyl)-1,3-propanediaminato](μ-asetato) nickel(II)}nickel(II)

The title compound, a homotrinuclear NiII complex has been synthesized from ONNO type Schiff base reduced with the help of NaBH4. The structure of the complex, [Ni{Ni(CH3CO2) (C17H20N2O2) (C3H7NO)}2], was identified using elemental analysis, thermal analysis, IR spectroscopy and x‐ray diffraction te...

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Bibliographic Details
Published in:Crystal research and technology (1979) 2002-12, Vol.37 (12), p.1352-1359
Main Authors: Tatar Yildirim, L., Atakol, O.
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
crystal structure
elemental analysis
Exact sciences and technology
Inorganic compounds
Metal complexes
NiII
Physics
Schiff base
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
thermal analysis
trinuclear complex
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Summary:The title compound, a homotrinuclear NiII complex has been synthesized from ONNO type Schiff base reduced with the help of NaBH4. The structure of the complex, [Ni{Ni(CH3CO2) (C17H20N2O2) (C3H7NO)}2], was identified using elemental analysis, thermal analysis, IR spectroscopy and x‐ray diffraction techniques. It was established that although some bond lengths and angles changed with respect to previous complexes, the Ni…Ni distance was approximately the same.
ISSN:0232-1300
1521-4079
DOI:10.1002/crat.200290013