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Lengthening the polymer solidification time to improve the performance of polymer/ZnO nanorod hybrid solar cells
Lengthening the polymer solidification time in the inverted configuration of polymer/ZnO nanorod hybrid solar cells is studied as a way to improve device performance. As the polymer solidification time is lengthened by lowering the spin-coating rate of the photoactive layer, the photoactive layer be...
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Published in: | Solar energy materials and solar cells 2009-09, Vol.93 (9), p.1608-1612 |
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container_end_page | 1612 |
container_issue | 9 |
container_start_page | 1608 |
container_title | Solar energy materials and solar cells |
container_volume | 93 |
creator | Chou, Chen-Yu Huang, Jing-Shun Wu, Chung-Hao Lee, Chun-Yu Lin, Ching-Fuh |
description | Lengthening the polymer solidification time in the inverted configuration of polymer/ZnO nanorod hybrid solar cells is studied as a way to improve device performance. As the polymer solidification time is lengthened by lowering the spin-coating rate of the photoactive layer, the photoactive layer becomes thickened, and the polymer chains have enough time to self-organize and effectively infiltrate into ZnO nanorod spacing. While the thickness of the photoactive layer is increased to 400
nm accompanying self-organized polymer, the power conversion efficiency of the device is improved to 3.58% with an enhanced fill factor of 58%. The 400
nm film is composed of the highly ordered polymer and the ZnO nanorod arrays, resulting in light harvesting without decreasing the possibility for charge transport. |
doi_str_mv | 10.1016/j.solmat.2009.04.016 |
format | article |
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issn | 0927-0248 1879-3398 |
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source | ScienceDirect Journals |
subjects | 400 nm active layer Applied sciences Energy Exact sciences and technology Hybrid solar cells Natural energy Photovoltaic conversion Polymer Slow drying Solar cells. Photoelectrochemical cells Solar energy ZnO nanorod |
title | Lengthening the polymer solidification time to improve the performance of polymer/ZnO nanorod hybrid solar cells |
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