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Comparative study of the rovibrational properties of heteronuclear alkali dimers in electric fields

A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their ${\rm X}^{1}\Sigma ^{+}$ electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and vario...

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Bibliographic Details
Published in:Europhysics letters 2008-08, Vol.83 (4), p.43001-43001(6)
Main Authors: González-Férez, R, Mayle, M, Sánchez-Moreno, P, Schmelcher, P
Format: Article
Language:English
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Summary:A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their ${\rm X}^{1}\Sigma ^{+}$ electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and various expectation values are presented. For moderate field strengths the electric-field$\hbox{--} $induced energy shifts, orientation, alignment, and angular-motion hybridization are analyzed up to high vibrational excitations close to the dissociation threshold.
ISSN:0295-5075
1286-4854
DOI:10.1209/0295-5075/83/43001