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Comparative study of the rovibrational properties of heteronuclear alkali dimers in electric fields
A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their ${\rm X}^{1}\Sigma ^{+}$ electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and vario...
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Published in: | Europhysics letters 2008-08, Vol.83 (4), p.43001-43001(6) |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | A comparative study of the effect of a static homogeneous electric field on the rovibrational spectra of several polar dimers in their ${\rm X}^{1}\Sigma ^{+}$ electronic ground state is performed. Focusing upon the rotational ground state within each vibrational band, results for energies and various expectation values are presented. For moderate field strengths the electric-field$\hbox{--} $induced energy shifts, orientation, alignment, and angular-motion hybridization are analyzed up to high vibrational excitations close to the dissociation threshold. |
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ISSN: | 0295-5075 1286-4854 |
DOI: | 10.1209/0295-5075/83/43001 |