X-ray initiated polymerization of wood impregnants

• Published in: Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2009-07, Vol.78 (7), p.535-538
• Main Authors: Cleland, Marshall R., Galloway, Richard A., Berejka, Anthony J., Montoney, Daniel, Driscoll, Mark, Smith, Leonard, Scott Larsen, L.
• Format: Article
• Language: English
• Subjects: Wood impregnation; Wood-polymer penetrant; X-ray polymerization
• ISSN: 0969-806X; 1879-0895
• DOI: 10.1016/j.radphyschem.2009.04.008

X-rays, derived from a high energy, high-current electron beam (EB), initiated in-situ polymerization of a unique class of monomers that were found to penetrate the cell walls of wood. X-rays initiated an auto-catalytic acrylic polymerization and penetrated through thick pieces of wood. The final cured product having the polymerizate, a polymer, both in the wood cell lumens and in the cell walls is called wood impregnated with a wood-polymer penetrant (WPP). The controlled lower dose rate of X-rays overcame disproportionation encountered when using higher dose-rate electron beam initiation. With X-rays, the in-situ polymerization took place in one exposure of modest dose. With EB, multiple passes were needed to avoid excessive heat build-up and monomer volatilization. Having entered the cell walls of the wood and then being polymerized within the cell walls, these radiation-cured unique monomers imparted outstanding dimensional stability upon exposure of the impregnated wood to humidity cycling. The preferred monomer system was also chemically modified prior to impregnation with agents that would remain in the wood and prevent the growth of fungi and other microbials. This technique differs from historic uses of monomers that merely filled the lumens of the wood (historic wood-polymer composites), which are only suitable for indoor use. The WPP impregnated wood that was either X-ray cured or EB cured demonstrated enhanced structural properties, dimensional stability, and decay resistance.