Disbonding of underwater-cured epoxy coating caused by cathodic protection current

• Published in: Corrosion science 2009-10, Vol.51 (10), p.2253-2258
• Main Authors: Martinez, Sanja, Žulj, Lidija Valek, Kapor, Frankica
• Format: Article
• Language: English
• Subjects: A. Low alloy steel; A. Organic coatings; Applied sciences; B. Polarization; C. Cathodic protection; Corrosion; Corrosion environments; Corrosion prevention; Exact sciences and technology; Metals. Metallurgy; Nonmetallic coatings; Production techniques; Surface treatment
• ISSN: 0010-938X; 1879-0496
• DOI: 10.1016/j.corsci.2009.06.003

Cathodic disbonding of the underwater-applied, ultra-thick, solvent free epoxy coating subjected to various levels of cathodic protection was investigated during the period of the coating cure. The results indicate that the partially cured coating was of low resistivity, between 10 3 and 10 5 Ω cm 2 for the cathodic polarization of on-potentials between −0.98 and −1.4 V Ag/AgCl/sw. The coating was shown to be capable of withstanding normal levels of cathodic protection between off-potentials of −0.8 and −1.1 V Ag/AgCl/sw while the IR drop, introduced by the coating in the same potential range, increased from 0.06 to 0.1 V and has to be taken into account at the design stage of the cathodic protection system. Beneficial influence of calcareous deposit formation on the cathodic protection current was confirmed, particularly for the failed coating. The initial period (1 week) of coating cure was shown as the most critical for disbonding processes caused by the excessive cathodic polarization.