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Phenoxazine and N-phenyl-1-naphtylamine-based enamines as hole-transporting glass-forming materials
New aromatic enamines were synthesized by condensation of the commercially available phenoxazine and N-phenyl-1-naphtylamine with 2,2-diphenylacetaldehyde or 2-phenylpropionaldehyde. The materials were examined by various techniques including differential scanning calorimetry, UV and fluorescence sp...
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| Published in: | Synthetic metals 2009-06, Vol.159 (11), p.1014-1018 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c439t-aefdeaa11648760a5794c5fe2f16f3d9c77d1a7d57fac0d34b9c3de514cd0ab03 |
| container_end_page | 1018 |
| container_issue | 11 |
| container_start_page | 1014 |
| container_title | Synthetic metals |
| container_volume | 159 |
| creator | Paspirgelyte, R. Grazulevicius, J.V. Grigalevicius, S. Jankauskas, V. |
| description | New aromatic enamines were synthesized by condensation of the commercially available phenoxazine and
N-phenyl-1-naphtylamine with 2,2-diphenylacetaldehyde or 2-phenylpropionaldehyde. The materials were examined by various techniques including differential scanning calorimetry, UV and fluorescence spectrometry, electron photoemission and time of flight techniques. The electron photoemission spectra of the layers of the amorphous materials showed the ionization potentials of 5.42–5.61
eV. Hole drift mobilities in the layers of 33–50% solid solutions of the derivatives in bisphenol Z polycarbonate range from 10
−5 to 3.4
×
10
−4
cm
2/V
s at high electric fields. |
| doi_str_mv | 10.1016/j.synthmet.2009.01.015 |
| format | article |
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N-phenyl-1-naphtylamine with 2,2-diphenylacetaldehyde or 2-phenylpropionaldehyde. The materials were examined by various techniques including differential scanning calorimetry, UV and fluorescence spectrometry, electron photoemission and time of flight techniques. The electron photoemission spectra of the layers of the amorphous materials showed the ionization potentials of 5.42–5.61
eV. Hole drift mobilities in the layers of 33–50% solid solutions of the derivatives in bisphenol Z polycarbonate range from 10
−5 to 3.4
×
10
−4
cm
2/V
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N-phenyl-1-naphtylamine with 2,2-diphenylacetaldehyde or 2-phenylpropionaldehyde. The materials were examined by various techniques including differential scanning calorimetry, UV and fluorescence spectrometry, electron photoemission and time of flight techniques. The electron photoemission spectra of the layers of the amorphous materials showed the ionization potentials of 5.42–5.61
eV. Hole drift mobilities in the layers of 33–50% solid solutions of the derivatives in bisphenol Z polycarbonate range from 10
−5 to 3.4
×
10
−4
cm
2/V
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eV. Hole drift mobilities in the layers of 33–50% solid solutions of the derivatives in bisphenol Z polycarbonate range from 10
−5 to 3.4
×
10
−4
cm
2/V
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| fulltext | fulltext |
| identifier | ISSN: 0379-6779 |
| ispartof | Synthetic metals, 2009-06, Vol.159 (11), p.1014-1018 |
| issn | 0379-6779 1879-3290 |
| language | eng |
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| source | ScienceDirect Journals |
| subjects | Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Conductivity of specific materials Electro-active material Electronic transport in condensed matter Enamine Equations of state, phase equilibria, and phase transitions Exact sciences and technology Glass transitions Hole drift mobility Ionization potential Physics Polymers organic compounds (including organic semiconductors) Specific phase transitions |
| title | Phenoxazine and N-phenyl-1-naphtylamine-based enamines as hole-transporting glass-forming materials |
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