Elaboration, characterization and application of polysulfone and polyacrylic acid blends as ultrafiltration membranes for removal of some heavy metals from water

• Published in: Journal of hazardous materials 2009-11, Vol.171 (1), p.93-101
• Main Authors: Mbareck, Chamekh, Nguyen, Quang Trong, Alaoui, Ouafa Tahiri, Barillier, Daniel
• Format: Article
• Language: English
• Subjects: Acrylic Resins - analysis; Applied sciences; Cadmium - analysis; Chemical engineering; Chromium - analysis; Exact sciences and technology; Filtration; Heavy metal; Hydrogen-Ion Concentration; Ion exchange; Ions; Lead; Membrane separation (reverse osmosis, dialysis...); Metals; Metals, Heavy - analysis; Metals, Heavy - isolation & purification; Microscopy, Electron, Scanning; Pollution; Polymer blends; Polymers - analysis; Porosity; SEM-EDX; Spectrophotometry, Atomic; Spectroscopy, Fourier Transform Infrared; Sulfones - analysis; Ultrafiltration membrane; Water - chemistry; Water depollution; Water Pollutants, Chemical - analysis; Water Purification - methods
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2009.05.123

Polysulfone (PSf)/polyacrylic acid ultrafiltration (PSf/PAA) membranes were prepared from a polymer blend in dimethylformamide by coagulation in water according to the wet phase inversion method. Immobilization of water-soluble PAA within the non-soluble PSf matrix was proven by the increase of ion exchange capacity and the intensity of the carboxyl groups’ peak with the increase of PAA content as shown by Fourier transform infrared spectra. These results lead to consider that PSf and PAA form a semi-interpenetrating polymer networks. The obtained membranes showed a decrease of mean surface-pore sizes, the overall porosity and the hydraulic permeability with the increase in PAA content. Such results were imputed to the morphologic modifications of PSf film with the immobilization of increasing PAA amount. PSf/PAA membranes showed high lead, cadmium and chromium rejection which reaches 100% at pH superior to 5.7 and a low rejection at low pH. Moreover, the heavy metal rejection decreases with feed solution concentration and applied pressure increases. These behaviors were attributed to the role of carboxylic groups in ion exchange or complexation. As a matter of fact, the strong lead ion–PAA interactions were revealed by the scanning electron microscopy with energy dispersive X-rays (SEM-EDX).