Effects of glass additions on the microstructure and dielectric properties of barium strontium titanate (BST) ceramics

• Published in: Journal of the European Ceramic Society 2010, Vol.30 (2), p.407-412
• Main Authors: Zhang, Dou, Button, Tim W., Sherman, Vladimir O., Tagantsev, Alexander K., Price, Tim, Iddles, David
• Format: Article
• Language: English
• Subjects: (Ba, Sr)TiO 3; Dielectric properties; Glass frit; Sintering
• ISSN: 0955-2219; 1873-619X
• DOI: 10.1016/j.jeurceramsoc.2009.05.003

Commercial glass frits (lead borosilicate glasses) were employed as the sintering aids to reduce the sintering temperatures of BST ceramics. The effects of the glass content and the sintering temperature on the microstructures, dielectric properties and tunabilities of BST ceramics have been investigated. Densification of BST ceramics of 5 wt% glass content becomes significant from sintering temperature of 1000 °C. The glass content shows a strong influence on the Curie temperature T c, permittivity and the diffuse transition. X-ray results show all BST ceramics exhibit a perovskite structure and also the formation of a secondary phase, Ba 2TiSi 2O 8. The shift of BST diffraction peaks towards higher angle with increasing the glass content indicates the substitution of Pb 2+ in Ba 2+ site, which mainly accounts for the diffuse transition observed in these BST ceramics. BST ceramics with 10 wt% glass additives possess the highest tunability at all four sintering temperatures. A tunability of 12.2% at a bias field of 1 kV/mm was achieved for BST ceramics with 10 wt% glass content sintered at 900 °C.