Fabrication and Characterization of High Temperature Resin/Carbon Nanofiber Composites

• Published in: High performance polymers 2006-08, Vol.18 (4), p.527-544
• Main Authors: Ghose, Sayata, Watson, Kent A., Working, Dennis C., Siochi, Emilie J., Connell, John W., Criss, Jim M.
• Format: Article
• Language: English
• ISSN: 0954-0083; 1361-6412
• DOI: 10.1177/0954008306066538

Multifunctional composites present a route to structural weight reduction. Nanoparticles such as carbon nanofibers (CNF) provide a compromise as a lower cost nanosize reinforcement that yields a desirable combination of properties. Blends of PETI-330 and CNFs were prepared and characterized to investigate the potential of CNF composites as a high-performance structural medium. Dry mixing techniques were employed and the effect of CNF loading level on melt viscosity was determined. The resulting powders were characterized for degree of mixing, thermal and rheological properties. Based on the characterization results, samples containing 30 and 40 wt.% CNF were scaled up to approximately 300 g and used to fabricate moldings 10.2 cm ′ 15.2 cm ′ 0.32 cm thick. The moldings were fabricated by injecting the mixtures at 260-280°C into a stainless steel tool followed by curing for 1 h at 371°C. The tool was designed to impart high shear during the injection process in an attempt to achieve some alignment of CNFs in the flow direction. Moldings were obtained that were subsequently characterized for thermal, mechanical and electrical properties. The degree of dispersion and alignment of CNFs were investigated using high-resolution scanning electron microscopy. The preparation and preliminary characterization of PETI-330/CNF composites are discussed.