Magnesium iron aluminum hydroxosalts and oxide catalysts for oxidative dehydrogenation of alkanes and alcohols

Methods are developed for the synthesis of precursors for oxide catalysts containing iron hydroxocarbonate and magnesium aluminum hydroxocarbonate with hydrotalcite-type layered structure and decavanadate and paramolybdate ions in anionic interlayers. These precursors are used to synthesize oxide ca...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2008-08, Vol.53 (8), p.1176-1181
Main Authors: Krasnobaeva, O. N., Belomestnykh, I. P., Isagulyants, G. V., Nosova, T. A., Elizarova, T. A., Kondakov, D. F., Danilov, V. P.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Synthesis and Properties of Inorganic Compounds
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Summary:Methods are developed for the synthesis of precursors for oxide catalysts containing iron hydroxocarbonate and magnesium aluminum hydroxocarbonate with hydrotalcite-type layered structure and decavanadate and paramolybdate ions in anionic interlayers. These precursors are used to synthesize oxide catalysts for oxidative dehydrogenation of alcohols and alkanes with high selectivity and good yields of the desired product in conversion of ethane to ethylene and alcohols to carbonyl compounds.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023608080044