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A Heterogeneous catalyst for efficient and green synthesis of 2-arylbenzothiazoles and 2-arylbenzimidazoles

Solid heteropoly acid supported on silica gel (Cu 3/2PMo 12O 40/SiO 2) is easily used as a heterogonous, reusable and efficient catalyst for synthesis of 2-arylbenzimidazoles and 2-arylbenzothiazoles by reaction of o-phenylenediamine and o-aminothiophenol with different aldehydes under various condi...

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Published in:Applied catalysis. A, General General, 2009-01, Vol.353 (1), p.74-79
Main Authors: Fazaeli, Razieh, Aliyan, Hamid
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Language:English
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description Solid heteropoly acid supported on silica gel (Cu 3/2PMo 12O 40/SiO 2) is easily used as a heterogonous, reusable and efficient catalyst for synthesis of 2-arylbenzimidazoles and 2-arylbenzothiazoles by reaction of o-phenylenediamine and o-aminothiophenol with different aldehydes under various conditions. The catalyst can be reused for several times but it will be less active. ▪ Solid heteropoly acid supported on silica gel (Cu 3/2PMo 12O 40/SiO 2) is easily used as a heterogonous, reusable and efficient catalyst for synthesis of 2-arylbenzimidazoles and 2-arylbenzothiazoles by reaction of o-phenylenediamine and o-aminothiophenol with different aldehydes under various conditions (in solvent, under solvent-free conditions, microwave and ultrasonic wave irradiation). The catalyst can be reused for several times but it will be less active.
doi_str_mv 10.1016/j.apcata.2008.10.035
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source ScienceDirect Freedom Collection
subjects 2-Arylbenzimidazoles
2-Arylbenzothiazoles
Catalysis
Chemistry
Exact sciences and technology
General and physical chemistry
Heterogeneous
Heteropoly acids (HPAs)
o-Aminothiophenols
o-Phenylenediamine (OPD)
Polyoxometalates (POMs)
Supported catalyst
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
title A Heterogeneous catalyst for efficient and green synthesis of 2-arylbenzothiazoles and 2-arylbenzimidazoles
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