Nanoscale complex metal cyanides and thermolysis thereof

• Published in: Solid state sciences 2008-10, Vol.10 (10), p.1305-1313
• Main Authors: Buchold, Daniel H.M., Feldmann, Claus
• Format: Article
• Language: English
• Subjects: Chemical synthesis methods; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Cyanide; Exact sciences and technology; Materials science; Methods of nanofabrication; Microemulsion; Nanocrystalline materials; Nanomaterial; Nanoscale materials and structures: fabrication and characterization; Nanoscale materials: clusters, nanoparticles, nanotubes, and nanocrystals; Oxide; Physics; Structure of solids and liquids; crystallography; Thermal decomposition
• ISSN: 1293-2558; 1873-3085
• DOI: 10.1016/j.solidstatesciences.2008.02.003

The complex metal cyanides Co 3[Co(CN) 6] 2, ‘Ni(CN) 2’, ‘Cu(CN)’ and M 2[Fe(CN) 6] (with M = Co 2+, Ni 2+, Cu 2+) were prepared as nanomaterials via a microemulsion approach. As-prepared materials turned out to be non-agglomerated and crystalline. In addition, particle size and shape, size distribution and color were investigated. The as-prepared complex cyanides were used as precursors for thermal decomposition to generate the pertinent oxide materials, namely Co 3O 4, NiO, CuO and CoFe 2O 4. Despite the thermal treatment, which was carried out at 520 °C, the resulting oxide particles were still on the nanoscale. Even a redispersion was possible and led to comparably low degree of agglomeration. When aiming at ‘Ni(CN) 2’ and ‘Cu(CN)’ nanoscale solids have been gained, whose chemical composition and crystal structure have not been described and verified till now. [Display omitted]