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Expanded graphite as a support for Ni/carbon composites

Expanded graphite decorated with nickel oxide particles (EG NiO) has been synthesized through electrochemical oxidation of natural graphite in an aqueous nickel nitrate solution followed by a heat treatment. EG NiO was used to prepare nickel/carbon composites using two techniques: (a) hydrogen reduc...

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Bibliographic Details
Published in:Carbon (New York) 2009-02, Vol.47 (2), p.513-518
Main Authors: Afanasov, I.М., Shornikova, O.N., Avdeev, V.V., Lebedev, O.I., Tendeloo, G. Van, Matveev, A.T.
Format: Article
Language:English
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Summary:Expanded graphite decorated with nickel oxide particles (EG NiO) has been synthesized through electrochemical oxidation of natural graphite in an aqueous nickel nitrate solution followed by a heat treatment. EG NiO was used to prepare nickel/carbon composites using two techniques: (a) hydrogen reduction of nickel oxide particles loaded on the expanded graphite surface and (b) pyrolysis of coal tar pitch-impregnated EG NiO blocks. The EG NiO as well as the nickel/carbon composites have been characterized by X-ray diffraction, scanning and transmission electron microscopy, energy dispersive X-ray spectroscopy and selected area electron diffraction.
ISSN:0008-6223
1873-3891
DOI:10.1016/j.carbon.2008.10.034