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Silver(I) compounds with perfluorinated aromatic thiols C6F5C6F4SH, C10F7SH, and C6F5SH as precursors for silver nanoparticles
Silver(I) compounds with perfluorinated aromatic thiols (4-nonafluorodiphenylthiol C6F5C6F4SH (HL), 2-heptafluoronaphthalenethiol C10F7SH (HL), and pentafluorothiophenol C6F5SH (HL), namely AgL (I), AgL (II), AgL (III), were prepared. The thermal properties of compounds I--III and the composition of...
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Published in: | Russian journal of inorganic chemistry 2008-02, Vol.53 (2), p.209-212 |
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Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Online Access: | Get full text |
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Summary: | Silver(I) compounds with perfluorinated aromatic thiols (4-nonafluorodiphenylthiol C6F5C6F4SH (HL), 2-heptafluoronaphthalenethiol C10F7SH (HL), and pentafluorothiophenol C6F5SH (HL), namely AgL (I), AgL (II), AgL (III), were prepared. The thermal properties of compounds I--III and the composition of thermolysis products were studied. By powder X-ray diffraction and electron microscopy, it was shown that thermolysis of compounds I--III under argon and thermolysis of compound III in air yield Ag nanoparticles. |
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ISSN: | 0036-0236 |
DOI: | 10.1007/s11502-008-2010-4 |