Structural Characterization and Luminescence Behavior of a Silver(I) 1D Polymeric Chain Constructed via a Bridge with Unusual 4,5-Diazospirobifluorene and Perchlorate

A new polymeric silver complex, [Ag2(L 2)(ClO4)2] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag2(L 2)]2+ dimer bridged with ClO4 -. The Ag···...

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Published in:Inorganic chemistry 2004-08, Vol.43 (16), p.4781-4783
Main Authors: Wang, Chih-Chieh, Yang, Cheng-Han, Tseng, Shih-Min, Lin, Sue-Yi, Wu, Ti-Yu, Fuh, Ming-Ren, Lee, Gene-Hsiang, Wong, Ken-Tsung, Chen, Ruei-Tang, Cheng, Yi-Ming, Chou, Pi-Tai
Format: Article
Language:English
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Summary:A new polymeric silver complex, [Ag2(L 2)(ClO4)2] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag2(L 2)]2+ dimer bridged with ClO4 -. The Ag···Ag distances are 2.776(1) and 4.575(1) Å incorporated by two L ligands and by a ClO4 - bridge, respectively.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic0351794