Synthesis of Novel Amorphous Boron Carbonitride Ceramics from the Borazine Derivative Copolymer via Hydroboration

A preceramic polymer for boron carbonitride was synthesized for the first time by the hydroboration of borazine derivatives, B-triethynyl, N-trimethyl borazine and borazine, without a catalyst. A homogeneous, amorphous boron carbonitride ceramic was prepared by the thermolysis of a hydroborated copo...

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Bibliographic Details
Published in:Inorganic chemistry 2004-08, Vol.43 (16), p.4796-4798
Main Authors: Jeon, Jong-Kyu, Uchimaru, Yuko, Kim, Dong-Pyo
Format: Article
Language:English
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Summary:A preceramic polymer for boron carbonitride was synthesized for the first time by the hydroboration of borazine derivatives, B-triethynyl, N-trimethyl borazine and borazine, without a catalyst. A homogeneous, amorphous boron carbonitride ceramic was prepared by the thermolysis of a hydroborated copolymer in an argon atmosphere.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic035254a