Unprecedented and Differently Applicable Pentagonal Units in a Dynamic Library: A Keplerate of the Type {(W)W5}12{Mo2}30

Magic pentagons: Exploitation of versatile pentagonal units/ligands has previously led to giant molybdenum oxide based curved species, including spherical Keplerates. Similar methodology is now also applicable to the related tungstate scenario (see corresponding basic central pentagonal unit in gree...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2009, Vol.48 (1), p.149-153
Main Authors: Schäffer, Christian, Merca, Alice, Bögge, Hartmut, Todea, Ana Maria, Kistler, Melissa L., Liu, Tianbo, Thouvenot, René, Gouzerh, Pierre, Müller, Achim
Format: Article
Language:English
Subjects:
Keplerates
nanostructures
pentagonal building blocks
polyoxometalates
tungsten
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Summary:Magic pentagons: Exploitation of versatile pentagonal units/ligands has previously led to giant molybdenum oxide based curved species, including spherical Keplerates. Similar methodology is now also applicable to the related tungstate scenario (see corresponding basic central pentagonal unit in green).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200804496