Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron

Bis-pinacolatodiboron reacts with [small alpha],[small beta]-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2004-08 (16), p.1854-1855
Main Authors: Bell, Nathan J, Cox, Andrew J, Cameron, Neil R, Evans, John S O, Marder, Todd B, Duin, Marcel A, Elsevier, Cornelis J, Baucherel, Xavier, Tulloch, Arran A D, Tooze, Robert P
Format: Article
Language:English
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Summary:Bis-pinacolatodiboron reacts with [small alpha],[small beta]-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.
ISSN:1359-7345
1364-548X
DOI:10.1039/b406052k