Solvent-driven dewetting and rim instability

An experimental method suitable for reproducible results has been used to investigate dewetting behavior of thin films of solvent-laden polymer. This solvent-driven dewetting enables one to change spreading coefficient by an order of magnitude that is not readily realizable in thermal dewetting and...

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Bibliographic Details
Published in:The Journal of chemical physics 2004-09, Vol.121 (9), p.4346-4351
Main Authors: Lee, Sarng H, Yoo, Pil J, Kwon, S Joon, Lee, Hong H
Format: Article
Language:English
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Summary:An experimental method suitable for reproducible results has been used to investigate dewetting behavior of thin films of solvent-laden polymer. This solvent-driven dewetting enables one to change spreading coefficient by an order of magnitude that is not readily realizable in thermal dewetting and to study polar interactions that have not been fully exploited experimentally. While the film instability is similar to that found in thermal dewetting, the rim instability is quite different. Two different types of the rim instability have been found. With a polar solvent, the rim instability changes from one type to another with increasing film thickness whereas the unstable rim becomes stable for an apolar solvent.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1770475