Diversity of Catalysis by an Imido-Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis

New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition.

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2009-01, Vol.131 (3), p.908-909
Main Authors: Peterson, Erik, Khalimon, Andrey Y, Simionescu, Razvan, Kuzmina, Lyudmila G, Howard, Judith A. K, Nikonov, Georgii I
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:New Imido hydride complex 1 catalyzes a variety of silylation reactions that proceed via initial substrate activation but not silane addition.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja8085388