Preconcentration and determination of trace metal ions from aqueous samples by newly developed gallic acid modified Amberlite XAD-16 chelating resin

• Published in: Journal of hazardous materials 2009-04, Vol.163 (1), p.295-301
• Main Authors: Sharma, R.K., Pant, Parul
• Format: Article
• Language: English
• Subjects: Adsorption; Amberlite XAD-16-gallic acid; Applied sciences; Chelating Agents - chemistry; Chemical engineering; Continental surface waters; Exact sciences and technology; Gallic Acid - chemistry; Hydrogen-Ion Concentration; Ion exchange; Ion Exchange Resins - chemistry; Ions; Metals - analysis; Metals - chemistry; Molecular Structure; Natural water pollution; Pollution; Polymers - chemistry; Preconcentration; Solutions; Water treatment and pollution
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2008.06.120

Gallic acid was immobilized on Amberlite XAD-16 by coupling it through –N N group. The resulting chelating resin AmberliteXAD-16 gallic acid, characterized by thermogravimetric analysis (TGA), infrared (IR) spectra and BET analysis, was used to preconcentrate Cr(III), Mn(II),Fe(III),Co(II), Ni(II) and Cu(II)ions. The resin was employed for the preconcentration of the metal ions present in river water and industrial area aqueous samples. Several parameters like effect of pH, effect of time, effect of sample volume and flow rate of sample were investigated. The sorption capacities for the resin were 216 μmol g −1, 180 μmol g −1, 403 μmol g −1, 281 μmol g −1, 250 μmol g −1 and 344 μmol g −1 for Cr(III), Mn(II), Fe(III), Co(II), Ni(II) and Cu(II) respectively. The preconcentration factors for Cr(III), Mn(II),Fe(III),Ni(II),Co(II) and Cu(II) were found out to be 300, 200, 400, 285.7, 300 and 400 respectively. The effect of various interfering ions was also studied. Results were validated by using standard addition method for river water sample.