Difluorophenylsulfanylmethyl Radical and Difluoromethylene Diradical Synthons:  gem-Difluoromethylene Building Block

Bromodifluorophenylsulfanylmethane has been demonstrated to be a highly versatile gem-difluoromethylene (CF2) building block via the reaction of difluorophenylsulfanylmethyl radical with olefins. gem-Difluoroalkenes and products containing a midchain CF2 group and with manipulatable functionality ca...

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Bibliographic Details
Published in:Journal of organic chemistry 2004-10, Vol.69 (20), p.6913-6915
Main Authors: REUTRAKUL, Vichai, THONGPAISANWONG, Thanchanok, TUCHINDA, Patoomratana, KUHAKARN, Chutima, POHMAKOTR, Manat
Format: Article
Language:English
Subjects:
Aliphatic compounds
Chemistry
Exact sciences and technology
Organic chemistry
Preparations and properties
Online Access:Get full text
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Summary:Bromodifluorophenylsulfanylmethane has been demonstrated to be a highly versatile gem-difluoromethylene (CF2) building block via the reaction of difluorophenylsulfanylmethyl radical with olefins. gem-Difluoroalkenes and products containing a midchain CF2 group and with manipulatable functionality can be readily synthesized. The first example of a gem-difluoromethylene radical synthon is also reported.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo0489768