The synthesis of analogs of shuangkangsu, a novel natural cycloperoxide glucoside from Lonicera japonica Thunb

Four novel optically pure cycloperoxide glucosides 9a, 9b, 10a, and 10b, analogs of shuangkangsu - a natural product with unusual skeleton and antivirus activity from the buds of Lonicera japonica Thunb, were firstly synthesized by employing peroxidation and glucosidation reactions from phthalaldehy...

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Bibliographic Details
Published in:Journal of asian natural products research 2009-02, Vol.11 (2), p.172-176
Main Authors: Tang, Yan-Bo, Huang, Long-Jiang, Li, Di-Zao, Zhang, Qing-Jian, Chen, Ruo-Yun, Yu, De-Quan
Format: Article
Language:English
Subjects:
Antiviral Agents - chemistry
Antiviral Agents - isolation & purification
Antiviral Agents - pharmacology
asymmetric synthesis
cycloperoxide glucosides
Dioxanes - chemistry
Dioxanes - isolation & purification
Dioxanes - pharmacology
Glucose - chemistry
Glucosides - chemistry
Glucosides - isolation & purification
Glucosides - pharmacology
Lonicera - chemistry
Molecular Structure
Monosaccharides - chemistry
Monosaccharides - isolation & purification
Monosaccharides - pharmacology
Natural products
o-Phthalaldehyde - chemistry
shuangkangsu
shuangkangsu analogs
Stereoisomerism
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Summary:Four novel optically pure cycloperoxide glucosides 9a, 9b, 10a, and 10b, analogs of shuangkangsu - a natural product with unusual skeleton and antivirus activity from the buds of Lonicera japonica Thunb, were firstly synthesized by employing peroxidation and glucosidation reactions from phthalaldehyde or 4,5-dichloro phthalaldehyde and glucose.
ISSN:1028-6020
1477-2213
DOI:10.1080/10286020802618985