A Five-Coordinate Homoleptic Organotitanium(III) Compound

Reversed Berry pseudorotation (see picture) results in a severely distorted trigonal‐bipyramidal geometry with C2v symmetry in the paramagnetic (d1) anion [Ti(C6F5)5]2−, which was obtained by the low‐temperature reaction of TiCl4⋅x Et2O and LiC6F5 and is the first homoleptic organometallic compound...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2004-10, Vol.43 (39), p.5225-5228
Main Authors: Alonso, Pablo J., Falvello, Larry R., Forniés, Juan, García-Monforte, M. Angeles, Menjón, Babil
Format: Article
Language:English
Subjects:
EPR spectroscopy
fluorinated ligands
homoleptic compounds
metal-carbon bonds
titanium
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Summary:Reversed Berry pseudorotation (see picture) results in a severely distorted trigonal‐bipyramidal geometry with C2v symmetry in the paramagnetic (d1) anion [Ti(C6F5)5]2−, which was obtained by the low‐temperature reaction of TiCl4⋅x Et2O and LiC6F5 and is the first homoleptic organometallic compound containing a [TiR5]2− unit.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200460111